IR laser enhancement of the H + H2 reaction on an accurate dipole moment surface

摘要: Abstract This Letter reports an accurate dipole moment surface for collinear H 3 . Using this surface, we examine the + 2 reaction synamics in infrared laser fields. IR light interacting with system via (A.E. Orel and W.H. Miller, Chem. Phys. Lett. 57 (1978) 362) has no effect on at moderate intensities (e.g. 10 12 W/cm ), interaction only becomes significant higher where other processes become important. However, shape of probability obtained by Miller using assumed shows remarkable agreement results more quantitative study.