CO-induced ring-slippage reactions of molybdenocene and tungstenocene carbonyl complexes. Electrochemical and elevated-pressure infrared evidence for an electron-transfer catalysis
作者： Sigrid Mönkeberg , Edith van Raaij , Herbert Kiesele , Hans-Herbert Brintzinger
DOI: 10.1016/0022-328X(89)87027-5
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摘要: Abstract Infrared studies at a CO pressure of 120 bar show (η 5 -C H ) 2 W(CO) to be completely resistant an excess in the absence oxidants, but cyclovoltammetric measurements with this complex and 3 )(η )W(CO) THF solution 0°C indicate that ring-slipped dicarbonyl is catalytically generated by one-electron oxidation tungstenocene monocarbonyl under ambient pressure. Similar results are found for reaction Mo(CO) CO.
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