Improved ferroelectricity and ferromagnetism of Eu-modified BiFeO3–BaTiO3 lead-free multiferroic ceramics
作者： Mijie Tian , Lin Zhou , Xiao Zou , Qiaoji Zheng , Lingling Luo
DOI: 10.1007/S10854-015-3564-4
关键词:
摘要: Multiferroic ceramics of 0.75Bi1−xEuxFeO3–0.25BaTiO3 + 1 mol% MnO2 were synthesized by a conventional solid state reaction method and the effects Eu doping on microstructure, ferroelectric, ferromagnetic piezoelectric properties investigated. All exhibit pure perovskite structure without any secondary phases. After addition Eu3+ ions, crystal is transformed from rhombohedral to tetragonal phase at x = 0.025. The ferroelectricity ferromagnetism are improved. For ceramic with 0.025, optimum remanent polarization 18.3 μC/cm2 good piezoelectricity 82 pC/N obtained. saturated magnetization Ms magnetism Mr improved 165 141 % increasing 0 0.175, respectively.
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M. Mahesh Kumar, V. R. Palkar, K. Srinivas, S. V. Suryanarayana, Ferroelectricity in a pure BiFeO3 ceramic Applied Physics Letters. ,vol. 76, pp. 2764- 2766 ,(2000) , 10.1063/1.126468
Dunmin Lin, K.W. Kwok, H.L.W. Chan, Effects of MnO2 on the microstructure and electrical properties of 0.94(K0.5Na0.5)NbO3–0.06Ba(Zr0.05Ti0.95)O3 lead-free ceramics Materials Chemistry and Physics. ,vol. 109, pp. 455- 458 ,(2008) , 10.1016/J.MATCHEMPHYS.2007.12.015
Zhongqiang Hu, Meiya Li, Jun Liu, Ling Pei, Jing Wang, Benfang Yu, Xingzhong Zhao, Structural Transition and Multiferroic Properties of Eu-Doped BiFeO3 Thin Films Journal of the American Ceramic Society. ,vol. 93, pp. 2743- 2747 ,(2010) , 10.1111/J.1551-2916.2010.03766.X
Yongxing Wei, Xiaotao Wang, Jintao Zhu, Xiaoli Wang, Jiangjiang Jia, Dielectric, Ferroelectric, and Piezoelectric Properties of BiFeO3–BaTiO3 Ceramics Journal of the American Ceramic Society. ,vol. 96, pp. 3163- 3168 ,(2013) , 10.1111/JACE.12475
Qing Qing Wang, Zhuo Wang, Xiao Qiang Liu, Xiang Ming Chen, Improved Structure Stability and Multiferroic Characteristics in CaTiO3-Modified BiFeO3 Ceramics Journal of the American Ceramic Society. ,vol. 95, pp. 670- 675 ,(2012) , 10.1111/J.1551-2916.2011.04824.X
XiaoMing Chen, XuXu Gong, TingNan Li, Yuan He, Peng Liu, None, Microstructure, dielectric and ferroelectric properties of (1−x)(0.94Bi0.5Na0.5TiO3–0.06BaTiO3)–xBiFeO3 lead-free ceramics synthesized via a high energy ball milling method Journal of Alloys and Compounds. ,vol. 507, pp. 535- 541 ,(2010) , 10.1016/J.JALLCOM.2010.08.012
Seung Wha Lee, Chul Sung Kim, Growth of multiferroics BiFeO3 thin films by sol–gel method Journal of Magnetism and Magnetic Materials. ,vol. 304, ,(2006) , 10.1016/J.JMMM.2006.02.219
Maria Teresa Buscaglia, Liliana Mitoseriu, Vincenzo Buscaglia, Ilaria Pallecchi, Massimo Viviani, Paolo Nanni, Antonio Sergio Siri, Preparation and characterisation of the magneto-electric xBiFeO3–(1−x)BaTiO3 ceramics Journal of the European Ceramic Society. ,vol. 26, pp. 3027- 3030 ,(2006) , 10.1016/J.JEURCERAMSOC.2006.02.023
Serhiy O. Leontsev, Richard E. Eitel, Dielectric and Piezoelectric Properties in Mn‐Modified (1−x)BiFeO3–xBaTiO3 Ceramics Journal of the American Ceramic Society. ,vol. 92, pp. 2957- 2961 ,(2009) , 10.1111/J.1551-2916.2009.03313.X
Kanwar Singh Nalwa, Ashish Garg, None, Phase evolution, magnetic and electrical properties in Sm-doped bismuth ferrite Journal of Applied Physics. ,vol. 103, pp. 044101- ,(2008) , 10.1063/1.2838483