作者: Olle Matsson , Kenneth C. Westaway
DOI: 10.1016/S0065-3160(08)60194-X
关键词:
摘要: Publisher Summary This chapter is concerned with secondary deuterium kinetic isotope effects. The illustrates some of the important recent advances in interpretation and uses these effects to elucidate reaction mechanisms. Other excellent reviews (KIEs) have also been discussed chapter. demonstrates ways which tritium KIEs can be used mechanisms reactions determine structure their transition states. Secondary a-deuterium widely mechanism S N Some significant studies illustrating principles are presented this In particular, advantages using both theoretical calculations experimental data solve problems emphasized