Acoustical and excess thermodynamic studies of molecular interaction in aqueous mixed solvent systems at 303, 308 and 313 K

作者: R Palani , A Geetha , None

DOI: 10.1080/00319100802562862

关键词:

摘要: Ultrasonic velocity (U), density (ρ) and viscosity (η) for the ternary liquid mixtures of water + propylene glycol tetrahydrofuran, dimethylformamide, dimethylsulphoxide 1,4-dioxane have been measured as a function composition at 303, 308 313 K. The experimental data used to calculate some excess thermodynamical parameters such (η E), free volume ( ), Gibb's energy (ΔG E) interaction parameter (d). results are discussed interpreted in terms structural specific predominated by hydrogen bonding.

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