Is there any sense to investigate volumetric and acoustic properties of more binary mixtures containing Ionic Liquids

作者: Małgorzata Musiał , Edward Zorębski , Monika Geppert-Rybczyńska

DOI: 10.1016/J.JCT.2015.03.010

关键词:

摘要: The excess speed of sound, molar volume and isentropic compressibility 52 binary mixtures containing Ionic Liquids at T = 298.15 K were calculated using selected literature sound density data. second components alcohols: methanol, or ethanol, 1-propanol, 2-propanol, 1-butanol other solvents: acetone, acetonitrile, tetrahydrofuran, dichloromethane dimethylsulfoxide. Balankina’s relative excesses, Xbal, i.e. the ratios between ideal quantities XE/Xid also determined to reduce structural impact pure absolute excesses. Analysis shows some patterns for concentration dependences large groups mixtures; thus, scheme influence anion cation solvent on excesses was proposed. It seems that presented analysis provide knowledge about without doing experimental work. is visible Xbal parameters can support interpretation interactions which occur solvent.

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