Stereospecific polymerization of propylene on systems TiX3-AlEt3
作者： L.A. Rishina , E.I. Vizen , F.S. Dyachkovsky , S.I. Troyanov , G.N. Mazo
DOI: 10.1016/0014-3057(84)90090-9
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摘要: Abstract It has been shown that replacement of Cl atoms by I and Br leads to decrease in the activity catalytis systems TiCl 3 -AlEt owing number active centres. This is probably due fact a group titanium bound halogen bridges, not single atom, involved act. The most effective way enhancing isospecificity centre induce iodine-containing compound act upon crystal surface. However, no simple correlation between stereospecificity systems, ion radii anions distances M-M M-X was found.
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