New type of tetrazine-substituted metallophthalocyanines by microwave irradiation: Synthesis and characterization
作者： Ece Tuǧba Saka , Nuri Yıldırım , Halit Kantekin
DOI: 10.1002/HC.20623
关键词:
摘要: 5,6-bis(4-methylphenyl)-2,3-dihydro-1,2,3,4-tetrazine 2 was synthesized by the dimerization of ethyl p-methylbenzoateformylhydrazone 1 in hydrazinehydrate solution. 2,3-bis(4-methylphenyl)-6,7,14,15-tetrahydro[1,2,3,4]tetrazino [2,3d][1,8, 4,5]benzodithia-diazecine-10,11-dicarbonitrile 4 sythesized cyclization reaction tetrazine monomer onto 1,2-bis-(2-iodoethylmercapto)-4,5-dicyanobenzene 3. Co(II) and Cu(II) phthalocyanine complexes were prepared dinitrile compound (4) with chlorides Co(II), Cu(II), DMAE at 175°C, 350 W a microwave oven for 10 min. Zn(II)-phthalocyanine complex acetate Zn(II) The new compounds characterized combination IR, 1H-NMR, 13CNMR, UV-vis, elemental analysis, MS spectral data. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:456–461, 2010; View this article online wileyonlinelibrary.com. DOI 10.1002/hc.20623
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