The reaction of Ir4(CO)12 with bases
作者： M. Angoletta , L. Malatesta , G. Caglio
DOI: 10.1016/S0022-328X(00)82534-6
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摘要: Abstract The reaction of Ir4(CO)12 with potassium hydroxide in methanol and/or sodium tetrahydrofuran leads to the carbonyliridate anions [HIr4(CO)11]−, [Ir6(CO)22]2−, [Ir8(CO)20]2−, [Ir6(CO)15]2− and [Ir(CO)4]− obtained as salts bulky cations. From these, tetranuclear carbonyl hydride H2Ir4(CO)11 hexanuclear compound Ir6(CO)16 are also obtained.
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sci-hub.se 参考文章(3)
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