Tailoring Porosity in Carbon Nanospheres for Lithium–Sulfur Battery Cathodes

作者: Scott Evers , Xiao Liang , Marine Cuisinier , Arnd Garsuch , Linda F. Nazar

DOI: 10.1021/NN404439R

关键词:

摘要: Porous hollow carbon spheres with different tailored pore structures have been designed as conducting frameworks for lithium–sulfur battery cathode materials that exhibit stable cycling capacity. By deliberately creating shell porosity and utilizing the interior void volume of the carbon spheres, sufficient space for sulfur storage as well as electrolyte pathways is guaranteed. The effect of different approaches to develop shell porosity is examined and compared in this study. The most highly optimized sulfur–porous carbon nanosphere …

参考文章(46)
Linlin Qiu, Shichao Zhang, Lan Zhang, Mingming Sun, Weikun Wang, Preparation and enhanced electrochemical properties of nano-sulfur/poly(pyrrole-co-aniline) cathode material for lithium/sulfur batteries Electrochimica Acta. ,vol. 55, pp. 4632- 4636 ,(2010) , 10.1016/J.ELECTACTA.2010.03.030
Lifen Xiao, Yuliang Cao, Jie Xiao, Birgit Schwenzer, Mark H. Engelhard, Laxmikant V. Saraf, Zimin Nie, Gregory J. Exarhos, Jun Liu, A Soft Approach to Encapsulate Sulfur: Polyaniline Nanotubes for Lithium‐Sulfur Batteries with Long Cycle Life Advanced Materials. ,vol. 24, pp. 1176- 1181 ,(2012) , 10.1002/ADMA.201103392
Yuan Yang, Guangyuan Zheng, Yi Cui, None, Nanostructured sulfur cathodes Chemical Society Reviews. ,vol. 42, pp. 3018- 3032 ,(2013) , 10.1039/C2CS35256G
Shu-Ru Chen, Yun-Pu Zhai, Gui-Liang Xu, Yan-Xia Jiang, Dong-Yuan Zhao, Jun-Tao Li, Ling Huang, Shi-Gang Sun, Ordered mesoporous carbon/sulfur nanocomposite of high performances as cathode for lithium–sulfur battery Electrochimica Acta. ,vol. 56, pp. 9549- 9555 ,(2011) , 10.1016/J.ELECTACTA.2011.03.005
Bruno Scrosati, Jürgen Garche, Lithium batteries: Status, prospects and future Journal of Power Sources. ,vol. 195, pp. 2419- 2430 ,(2010) , 10.1016/J.JPOWSOUR.2009.11.048
Guangyuan Zheng, Yuan Yang, Judy J Cha, Seung Sae Hong, Yi Cui, None, Hollow Carbon Nanofiber-Encapsulated Sulfur Cathodes for High Specific Capacity Rechargeable Lithium Batteries Nano Letters. ,vol. 11, pp. 4462- 4467 ,(2011) , 10.1021/NL2027684
Jiacheng Wang, Stefan Kaskel, KOH activation of carbon-based materials for energy storage Journal of Materials Chemistry. ,vol. 22, pp. 23710- 23725 ,(2012) , 10.1039/C2JM34066F
Junghoon Kim, Dong-Ju Lee, Hun-Gi Jung, Yang-Kook Sun, Jusef Hassoun, Bruno Scrosati, An Advanced Lithium-Sulfur Battery Advanced Functional Materials. ,vol. 23, pp. 1076- 1080 ,(2013) , 10.1002/ADFM.201200689
Xiulei Ji, Kyu Tae Lee, Linda F. Nazar, A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries Nature Materials. ,vol. 8, pp. 500- 506 ,(2009) , 10.1038/NMAT2460
Mumin Rao, Haimei Zheng, Liang Zhang, Yuanchang Li, Wenhui Duan, Jinghua Guo, Elton J. Cairns, Yuegang Zhang, Liwen Ji, Graphene oxide as a sulfur immobilizer in high performance lithium/sulfur cells Journal of the American Chemical Society. ,vol. 133, pp. 18522- 18525 ,(2012) , 10.1021/JA206955K