Übergangsmetall-Carben-Komplexe : IX. Über die cis-trans-isomerisierung von [N-Methylamino)- methylcarben] pentacarbonylchrom(0) mittels basen
作者： E. Moser , E.O. Fischer
DOI: 10.1016/S0022-328X(00)86334-2
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摘要: Abstract The reaction of [cis-(N-Methylamino)methylcarbene]pentacarbonyl chromium (0) with bases yields a mixture the cis- and trans-isomers. reversible isomerization proceeds possibly via an anion that is formed by abstraction proton from nitrogen atom.
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