Photolysis of Particulate Nitrate as a Source of HONO and NOx

作者: Chunxiang Ye , Ning Zhang , Honglian Gao , Xianliang Zhou

DOI: 10.1021/ACS.EST.7B00387

关键词:

摘要: Photolysis of nitric acid on the surface has been found recently to be greatly enhanced from that in the gas phase. Yet, photolysis of particulate nitrate (pNO₃) associated with atmospheric aerosols is still relatively unknown. Here, aerosol filter samples were collected both near the ground surface and throughout the troposphere on board the NSF/NACR C-130 aircraft. The photolysis rate constants of pNO₃ were determined from these samples by directly monitoring the production rates of nitrous acid (HONO) and nitrogen dioxide (NO₂) …

参考文章(51)
A Gelencser, A Hoffer, G Kiss, E Tombacz, R Kurdi, L Bencze, In-situ formation of light-absorbing organic matter in cloud water Journal of Atmospheric Chemistry. ,vol. 45, pp. 25- 33 ,(2003) , 10.1023/A:1024060428172
C. Ye, X. Zhou, D. Pu, J. Stutz, J. Festa, M. Spolaor, C. Cantrell, R. L. Mauldin, A. Weinheimer, J. Haggerty, Comment on “Missing gas-phase source of HONO inferred from Zeppelin measurements in the troposphere” Science. ,vol. 348, pp. 1326- 1326 ,(2015) , 10.1126/SCIENCE.AAA1992
Fu-Ming Tao, Kelly Higgins, William Klemperer, David D. Nelson, Structure, binding energy, and equilibrium constant of the nitric acid‐Water complex Geophysical Research Letters. ,vol. 23, pp. 1797- 1800 ,(1996) , 10.1029/96GL00947
H. Lignell, M. L. Hinks, S. A. Nizkorodov, Exploring matrix effects on photochemistry of organic aerosols Proceedings of the National Academy of Sciences of the United States of America. ,vol. 111, pp. 13780- 13785 ,(2014) , 10.1073/PNAS.1322106111
Konrad Stemmler, Markus Ammann, Chantal Donders, Jörg Kleffmann, Christian George, Photosensitized reduction of nitrogen dioxide on humic acid as a source of nitrous acid Nature. ,vol. 440, pp. 195- 198 ,(2006) , 10.1038/NATURE04603
Harald J. Beine, Florent Dominé, William Simpson, Richard E. Honrath, Roberto Sparapani, Xianliang Zhou, Martin King, Snow-pile and chamber experiments during the Polar Sunrise Experiment ‘Alert 2000’: exploration of nitrogen chemistry Atmospheric Environment. ,vol. 36, pp. 2707- 2719 ,(2002) , 10.1016/S1352-2310(02)00120-6
Chong Han, Yongchun Liu, Hong He, Heterogeneous photochemical aging of soot by NO2 under simulated sunlight Atmospheric Environment. ,vol. 64, pp. 270- 276 ,(2013) , 10.1016/J.ATMOSENV.2012.10.008
Trevor C. VandenBoer, Cora J. Young, Ranajit K. Talukdar, Milos Z. Markovic, Steven S. Brown, James M. Roberts, Jennifer G. Murphy, Nocturnal loss and daytime source of nitrous acid through reactive uptake and displacement Nature Geoscience. ,vol. 8, pp. 55- 60 ,(2015) , 10.1038/NGEO2298
Jörg Kleffmann, Daytime Sources of Nitrous Acid (HONO) in the Atmospheric Boundary Layer ChemPhysChem. ,vol. 8, pp. 1137- 1144 ,(2007) , 10.1002/CPHC.200700016
Guillermo Villena, Jörg Kleffmann, Ralf Kurtenbach, Peter Wiesen, Eduardo Lissi, Maria A. Rubio, Giovanna Croxatto, Bernhard Rappenglück, Vertical gradients of HONO, NOx and O3 in Santiago de Chile Atmospheric Environment. ,vol. 45, pp. 3867- 3873 ,(2011) , 10.1016/J.ATMOSENV.2011.01.073