Synthesis of WO 3 catalytic powders: evaluation of photocatalytic activity under NUV/visible light irradiation and alkaline reaction pH

作者: I. Vamvasakis , I. Georgaki , D. Vernardou , G. Kenanakis , N. Katsarakis

DOI: 10.1007/S10971-015-3758-5

关键词:

摘要: WO3 catalytic powders were successfully synthesized from tungstic acid and sodium tungstate precursors by simple, low-cost sol–gel precipitation methods followed low-temperature hydrothermal treatment. crystallization process was completed with calcination of the samples at 500 700 °C. The effects synthesis method temperature on structural, morphological characteristics surface area investigated. photocatalytic activity evaluated discoloration efficiency methylene blue (MB) aqueous solutions under NUV/visible light irradiation various reaction pH values. MB found to increase increasing pH, best results obtained 9.

参考文章(23)
L'ubica Adamčíková, Katarína Pavlíková, Peter Ševčík, The Decay of Methylene Blue in Alkaline Solution Reaction Kinetics and Catalysis Letters. ,vol. 69, pp. 91- 94 ,(2000) , 10.1023/A:1005696926749
Xu Chun Song, Yi Fan Zheng, E. Yang, Yun Wang, Large-scale hydrothermal synthesis of WO3 nanowires in the presence of K2SO4 Materials Letters. ,vol. 61, pp. 3904- 3908 ,(2007) , 10.1016/J.MATLET.2006.12.055
Andrew Mills, David Hazafy, John Parkinson, Tell Tuttle, Michael G. Hutchings, Effect of alkali on methylene blue (C.I. Basic Blue 9) and other thiazine dyes Dyes and Pigments. ,vol. 88, pp. 149- 155 ,(2011) , 10.1016/J.DYEPIG.2010.05.015
Gratian R Bamwenda, Hironori Arakawa, The visible light induced photocatalytic activity of tungsten trioxide powders Applied Catalysis A-general. ,vol. 210, pp. 181- 191 ,(2001) , 10.1016/S0926-860X(00)00796-1
Khaled Melghit, Moza S. Al-Rubaei, Issa Al-Amri, Photodegradation enhancement of Congo red aqueous solution using a mixture of SnO2·xH2O gel/ZnO powder Journal of Photochemistry and Photobiology A-chemistry. ,vol. 181, pp. 137- 141 ,(2006) , 10.1016/J.JPHOTOCHEM.2005.11.015
Ralph W. Matthews, Stephen R. McEvoy, Photocatalytic degradation of phenol in the presence of near-UV illuminated titanium dioxide Journal of Photochemistry and Photobiology A: Chemistry. ,vol. 64, pp. 231- 246 ,(1992) , 10.1016/1010-6030(92)85110-G
Kazuhiro Sayama, Hiroki Hayashi, Takeo Arai, Masatoshi Yanagida, Takahiro Gunji, Hideki Sugihara, Highly active WO3 semiconductor photocatalyst prepared from amorphous peroxo-tungstic acid for the degradation of various organic compounds Applied Catalysis B-environmental. ,vol. 94, pp. 150- 157 ,(2010) , 10.1016/J.APCATB.2009.11.003
I. Jiménez, M. A. Centeno, R. Scotti, F. Morazzoni, J. Arbiol, A. Cornet, J. R. Morante, NH3 interaction with chromium-doped WO3 nanocrystalline powders for gas sensing applications Journal of Materials Chemistry. ,vol. 14, pp. 2412- 2420 ,(2004) , 10.1039/B400872C
Mohamed Mokhtar Mohamed, I. Othman, R.M. Mohamed, Synthesis and characterization of MnOx/TiO2 nanoparticles for photocatalytic oxidation of indigo carmine dye Journal of Photochemistry and Photobiology A: Chemistry. ,vol. 191, pp. 153- 161 ,(2007) , 10.1016/J.JPHOTOCHEM.2007.04.017