Synthesis, structure, and properties of [Mn(salpn)(EtOH)2](ClO4) and its aerobic oxidation product [Mn(salpn)O]2

作者: Joel W. Gohdes , William H. Armstrong

DOI: 10.1021/IC00029A007

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摘要: Preparation and isolation of the mononuclear Mn III complex [Mn(salpn)(EtOH) 2 ](ClO 4 ) (1a) (H salpn=N,N'-bis(salicylidene)-1,3-diaminopropane) were accomplished by air oxidation a solution containing H salpn, NaOH, Mn(ClO .6H O in MeOH/EtOh (1:1), followed addition Et

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