Iridium‐EDTA as an Efficient and Readily Available Catalyst for Water Oxidation
作者： Arianna Savini , Gianfranco Bellachioma , Sandra Bolaño , Luca Rocchigiani , Cristiano Zuccaccia
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摘要: It′s so easy: The readily available and highly water‐soluble [IrCl(Hedta)]Na complex is an efficient robust catalyst for water oxidation to molecular oxygen. reaction driven by the reduction of Ce4+ Ce3+. Its performances (TOF=6.8 min−1 TON>12 000) are derived UV/Vis spectroscopic, volumetric electrochemical measurements, compare favorably with those best catalysts reported far.
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Feng Jiao, Heinz Frei, Nanostructured cobalt and manganese oxide clusters as efficient water oxidation catalysts Energy and Environmental Science. ,vol. 3, pp. 1018- 1027 ,(2010) , 10.1039/C002074E
Ralte Lalrempuia, Neal D. McDaniel, Helge Müller-Bunz, Stefan Bernhard, Martin Albrecht, Katalytische Oxidation von Wasser durch einen Iridiumkomplex mit einem starken Carben‐Donorliganden Angewandte Chemie. ,vol. 122, pp. 9959- 9962 ,(2010) , 10.1002/ANGE.201005260
Jonathan F. Hull, David Balcells, James D. Blakemore, Christopher D. Incarvito, Odile Eisenstein, Gary W. Brudvig, Robert H. Crabtree, Highly Active and Robust Cp* Iridium Complexes for Catalytic Water Oxidation Journal of the American Chemical Society. ,vol. 131, pp. 8730- 8731 ,(2009) , 10.1021/JA901270F
Susan W. Gersten, George J. Samuels, Thomas J. Meyer, Catalytic oxidation of water by an oxo-bridged ruthenium dimer Journal of the American Chemical Society. ,vol. 104, pp. 4029- 4030 ,(1982) , 10.1021/JA00378A053
N. S. Lewis, D. G. Nocera, Powering the planet: Chemical challenges in solar energy utilization Proceedings of the National Academy of Sciences of the United States of America. ,vol. 103, pp. 15729- 15735 ,(2006) , 10.1073/PNAS.0603395103
Cristina Sens, Isabel Romero, Montserrat Rodríguez, Antoni Llobet, Teodor Parella, Jordi Benet-Buchholz, A new Ru complex capable of catalytically oxidizing water to molecular dioxygen Journal of the American Chemical Society. ,vol. 126, pp. 7798- 7799 ,(2004) , 10.1021/JA0486824
Xavier Sala, Isabel Romero, Montserrat Rodríguez, Lluís Escriche, Antoni Llobet, Molekulare Katalysatoren für die Oxidation von Wasser zu Disauerstoff Angewandte Chemie. ,vol. 121, pp. 2882- 2893 ,(2009) , 10.1002/ANGE.200802659
Alex A. Diamantis, Jules V. Dubrawski, Preparation and structure of ethylenediaminetetraacetate complexes of ruthenium(II) with dinitrogen, carbon monoxide, and other .pi.-acceptor ligands Inorganic Chemistry. ,vol. 12, pp. 1142- 1150 ,(1981) , 10.1021/IC50218A037
Wolfgang Rüttinger, G. Charles Dismukes, Synthetic Water-Oxidation Catalysts for Artificial Photosynthetic Water Oxidation. Chemical Reviews. ,vol. 97, pp. 1- 24 ,(1997) , 10.1021/CR950201Z
Masayuki Yagi, Masao Kaneko, Molecular catalysts for water oxidation. Chemical Reviews. ,vol. 101, pp. 21- 35 ,(2001) , 10.1021/CR980108L