A fluorescent receptor for halide recognition: clues for the design of anion chemosensors.
作者： Riccardo Chelli , Giangaetano Pietraperzia , Andrea Bencini , Claudia Giorgi , Vito Lippolis
DOI: 10.1039/C5CP00131E
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摘要: The chemosensing properties of the polyaza-macrocycle 1-(6,7)-acridine-3,6,9,12-tetraaza-tridecaphane have been investigated by means emission fluorescence spectroscopy, considering halide ions as substrates. As in case free ligand, complexes is due to acridinium species which are formed after photoinduced proton transfer reaction. complexation constants obtained for bi- and tri-protonated ligands deoxygenated aqueous solutions. Two different behaviours observed varying anion. Fluoride chloride give rise enhancement whereas bromide iodide strongly quench emission. macrocycle shows an unusual higher selectivity towards anion rather than fluoride. has modelled a modified Stern–Volmer equation, taking into account quenching effects largest anions, can be considered negligible fluoride anions. Ab initio calculations allow us interpret terms activation energy related reaction responsible process.
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Beth A. McNally, Atanas V. Koulov, Bradley D. Smith, Jean-Baptiste Joos, Anthony P. Davis, A fluorescent assay for chloride transport; identification of a synthetic anionophore with improved activity Chemical Communications. pp. 1087- 1089 ,(2005) , 10.1039/B414589E
Anthony P. Davis, Jean-Baptiste Joos, Steroids as organising elements in anion receptors Coordination Chemistry Reviews. ,vol. 240, pp. 143- 156 ,(2003) , 10.1016/S0010-8545(03)00020-1
Sulaiman Ayoob, Ashok Kumar Gupta, None, Fluoride in Drinking Water: A Review on the Status and Stress Effects Critical Reviews in Environmental Science and Technology. ,vol. 36, pp. 433- 487 ,(2006) , 10.1080/10643380600678112
Chunyang Peng, H. Bernhard Schlegel, Combining Synchronous Transit and Quasi-Newton Methods to Find Transition States Israel Journal of Chemistry. ,vol. 33, pp. 449- 454 ,(1993) , 10.1002/IJCH.199300051
Sean D. Reilly, Guru Rattan K. Khalsa, Doris K. Ford, James R. Brainard, Benjamin P. Hay, Paul H. Smith, Octaazacryptand Complexation of the Fluoride Ion Inorganic Chemistry. ,vol. 34, pp. 569- 575 ,(1995) , 10.1021/IC00107A008
Markus Flury, Andreas Papritz, Bromide in the Natural Environment: Occurrence and Toxicity Journal of Environmental Quality. ,vol. 22, pp. 747- 758 ,(1993) , 10.2134/JEQ1993.00472425002200040017X
Jacopo Tomasi, Benedetta Mennucci, Roberto Cammi, Quantum Mechanical Continuum Solvation Models Chemical Reviews. ,vol. 105, pp. 2999- 3094 ,(2005) , 10.1021/CR9904009
Christos A. Ilioudis, Derek A. Tocher, Jonathan W. Steed, A highly efficient, preorganized macrobicyclic receptor for halides based on CH... and NH...anion interactions. Journal of the American Chemical Society. ,vol. 126, pp. 12395- 12402 ,(2004) , 10.1021/JA047070G
Ramón Martínez-Máñez, Félix Sancenón, Fluorogenic and chromogenic chemosensors and reagents for anions. Chemical Reviews. ,vol. 103, pp. 4419- 4476 ,(2003) , 10.1021/CR010421E
Masato Hirai, François P. Gabbaï, Lewis acidic stiborafluorenes for the fluorescence turn-on sensing of fluoride in drinking water at ppm concentrations Chemical Science. ,vol. 5, pp. 1886- 1893 ,(2014) , 10.1039/C4SC00343H