Study on the combustion behavior of high impact polystyrene nanocomposites produced by different extrusion processes
作者： G. Sanchez-Olivares , A. Sanchez-Solis , G. Camino , O. Manero
DOI: 10.3144/EXPRESSPOLYMLETT.2008.69
关键词:
摘要: The combustion behavior of a blend made high impact polystyrene (HIPS) with sodium montmorillonite (MMT-Na+) and triphenyl phosphite (TPP), as halogen-free flame retardant, is analyzed in detail this work. processed through various extrusion methods aimed to improve clay dispersion. UL94 method vertical position, oxygen index cone calorimetric measurements assess HIPS combustion. TGA, FTIR, SEM X-ray measurements, together mechanical rheological tests evaluate the thermal degradation, morphology, intercalation degree dispersion particles. use static-mixing die placed at extreme single screw extruder improves platelets distribution reduces peak heat release rate better than employing twin process. In addition, properties are affected substantially by changing A correlation between fire retardant found, decreases good tests.
sci-hub.st 参考文章(28)
G. W. Beall, Thomas J. Pinnavaia, Polymer-clay nanocomposites John Wiley. ,(2000)
Flame retardant polymer nanocomposites Wiley-Interscience. ,(2007) , 10.1002/0470109033
Daimay Lin-Vien, The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules ,(1991)
A. Sanchez-Solis, A. Garcia-Rejon, O. Manero, Production of nanocomposites of PET-montmorillonite clay by an extrusion process Macromolecular Symposia. ,vol. 192, pp. 281- 292 ,(2003) , 10.1002/MASY.200390038
A. Sánchez-Solís, I. Romero-Ibarra, M. R. Estrada, F. Calderas, O. Manero, Mechanical and rheological studies on polyethylene terephthalate-montmorillonite nanocomposites Polymer Engineering & Science. ,vol. 44, pp. 1094- 1102 ,(2004) , 10.1002/PEN.20102
Ke Wang, Si Liang, Rongni Du, Qin Zhang, Qiang Fu, The interplay of thermodynamics and shear on the dispersion of polymer nanocomposite Polymer. ,vol. 45, pp. 7953- 7960 ,(2004) , 10.1016/J.POLYMER.2004.09.053
B. Marosföi, Sz. Matko, P. Anna Gy. Marosi, Fire retarded polymer nanocomposites Current Applied Physics. ,vol. 6, pp. 259- 261 ,(2006) , 10.1016/J.CAP.2005.07.052
A. Granzow, C. Savides, Flame retardancy of polypropylene and impact polystyrene: Phosphonium bromide/ammonium polyphosphate system Journal of Applied Polymer Science. ,vol. 25, pp. 2195- 2204 ,(1980) , 10.1002/APP.1980.070251006
F. A. Miller, C. H. Wilkins, Infrared Spectra and Characteristic Frequencies of Inorganic Ions Analytical Chemistry. ,vol. 24, pp. 1253- 1294 ,(1952) , 10.1021/AC60068A007
B. Schartel, M. Bartholmai, U. Knoll, Some comments on the use of cone calorimeter data Polymer Degradation and Stability. ,vol. 88, pp. 540- 547 ,(2005) , 10.1016/J.POLYMDEGRADSTAB.2004.12.016