Architectural control of sugar-containing polymers by living polymerization : ring-opening polymerization of 2-oxazolines initiated with carbohydrate derivatives

摘要: Living polymerization of 2-oxazolines with bicyclic N-acetyl-D-glucosamines yielded new types inter-sugar distance controllable synthetic glycoconjugates. Furthermore, a graft copolymer consisting sugar moiety at the end side chain, an oligo(2-oxazoline) spacer unit in chain and oligostyrene backbone was prepared by radical copolymerization styrene monodisperse ω-acryl-type poly(2-oxazoline) macromonomer