Breakdown Phenomena During the Growth of Anodic Films on Antimony
作者： Ch. Girginov , E. Lilov , E. Klein
DOI: 10.1007/978-94-017-9697-2_30
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摘要: Electrical breakdown during galvanostatic and isothermal growth of Sb2O3-films in aqueous solutions sulfuric, boric, phosphoric oxalic acid was analyzed. The voltage registered at the onset oscillations forming voltage. boric electrolytes were accompanied by acoustic emission. number events, amplitude energy waves registered. values these parameters did not differ essentially from very beginning process. effects current density nature concentration electrolyte on value studied. results obtained do contradict concepts dielectric anodic films under impact electric field applied. Breakdown has been ascribed to injection electrons into bulk oxide their acceleration multiplication an avalanche.
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sci-hub.st 参考文章(29)
Lawrence Young, Anodic oxide films. Part 4.—The interpretation of impedance measurements on oxide coated electrodes on niobium Trans. Faraday Soc.. ,vol. 51, pp. 1250- 1260 ,(1955) , 10.1039/TF9555101250
M. Metiko≥Huković, B. Lovrec̆ek, Electrochemical behaviour of the oxide covered antimony Electrochimica Acta. ,vol. 25, pp. 717- 723 ,(1980) , 10.1016/0013-4686(80)87084-8
End Semester Mph B, Physics of Semiconductor Devices ,(2009)
I.A. Ammar, A. Saad, Anodic oxide film on antimony : I. Role of experimental conditions and growth kinetics in acid media Journal of Electroanalytical Chemistry. ,vol. 30, pp. 395- 406 ,(1971) , 10.1016/0368-1874(71)87023-5
V. Kadary, N. Klein, Electrical Breakdown I . During the Anodic Growth of Tantalum Pentoxide Journal of The Electrochemical Society. ,vol. 127, pp. 139- 151 ,(1980) , 10.1149/1.2129604
S. Gudić, J. Radošević, M. Kliškić, Impedance and transient study of aluminium barrier-type oxide films Journal of Applied Electrochemistry. ,vol. 26, pp. 1027- 1035 ,(1996) , 10.1007/BF00242197
M. Bojinov, I. Kanazirski, A. Girginov, Anodic film growth on antimony in H3PO4 solutions Electrochimica Acta. ,vol. 40, pp. 873- 878 ,(1995) , 10.1016/0013-4686(94)00344-Z
Yi Li, Hideki Shimada, Masatoshi Sakairi, Kazuhiro Shigyo, Hideaki Takahashi, Masahiro Seo, Formation and Breakdown of Anodic Oxide Films on Aluminum in Boric Acid/Borate Solutions Journal of The Electrochemical Society. ,vol. 144, pp. 866- 876 ,(1997) , 10.1149/1.1837501
L. Young, The contribution of microfissures to the dielectric losses of anodic oxide films on tantalum and zirconium and their role in electrolytic rectification Transactions of the Faraday Society. ,vol. 55, pp. 842- 849 ,(1959) , 10.1039/TF9595500842
A.S Mogoda, T.M Abd El-Haleem, Anodic oxide film formation on antimony and its currentless dissolution in sulphuric acid containing some monocarboxylic acids Thin Solid Films. ,vol. 441, pp. 6- 12 ,(2003) , 10.1016/S0040-6090(03)00876-9