Tricolor electrochromism of copolymer based on selenophene and 3,4-ethylenedioxythiophene

作者: Xiao-qian Xu , Wen-wei Zheng , Yi-jie Tao , Hai-feng Cheng , Zhao-yang Zhang

DOI: 10.1016/J.SYNTHMET.2012.11.026

关键词:

摘要: Abstract A copolymer based on selenophene and 3,4-ethylenedioxythiophene was successfully synthesized by electrochemical polymerization in boron trifluoride diethyl etherate (BFEE). The resultant characterized cyclic voltammetry, FTIR, XPS, SEM spectroelectrochemistry. presented tricolor electrochromism, which dark green-yellow (in the neutral state), blue-green intermediate state) blue oxidized state). Furthermore, optical contrast switching time of found to be 19.8% 3.2 s at 728 nm, respectively, remained 75.1% its original electroactivity after 200 cycles.

参考文章(24)
Roger J. Mortimer, Aubrey L. Dyer, John R. Reynolds, Electrochromic organic and polymeric materials for display applications Displays. ,vol. 27, pp. 2- 18 ,(2006) , 10.1016/J.DISPLA.2005.03.003
Bin Wang, Jinsheng Zhao, Chuansheng Cui, Renmin Liu, Jifeng Liu, Huaisheng Wang, Houting Liu, Electrochromic properties of a novel low band gap conjugated copolymer based on 1,4-bis(2-thienyl)-naphthalene and 3,4-ethylenedioxythiophene Electrochimica Acta. ,vol. 56, pp. 4819- 4827 ,(2011) , 10.1016/J.ELECTACTA.2011.03.020
Yi-jie Tao, Hai-feng Cheng, Wen-wei Zheng, Zhao-yang Zhang, Dong-qing Liu, Electrosynthesises and characterizations of copolymers based on pyrrole and 3,4-ethylenedioxythiophene in aqueous micellar solution Synthetic Metals. ,vol. 162, pp. 728- 734 ,(2012) , 10.1016/J.SYNTHMET.2012.02.003
Pierre M. Beaujuge, Chad M. Amb, John R. Reynolds, Spectral engineering in π-conjugated polymers with intramolecular donor-acceptor interactions. Accounts of Chemical Research. ,vol. 43, pp. 1396- 1407 ,(2010) , 10.1021/AR100043U
Guangming Nie, Liangyan Qu, Jingkun Xu, Shusheng Zhang, Electrosyntheses and characterizations of a new soluble conducting copolymer of 5-cyanoindole and 3,4-ethylenedioxythiophene Electrochimica Acta. ,vol. 53, pp. 8351- 8358 ,(2008) , 10.1016/J.ELECTACTA.2008.06.058
Jürgen Heinze, Bernardo A. Frontana-Uribe, Sabine Ludwigs, Electrochemistry of Conducting Polymers—Persistent Models and New Concepts† Chemical Reviews. ,vol. 110, pp. 4724- 4771 ,(2010) , 10.1021/CR900226K
Pinar Camurlu, Simge Tarkuç, Ertuğrul Şahmetlioğlu, İdris Mecidoğlu Akhmedov, Cihangir Tanyeli, Levent Toppare, Multichromic conducting copolymer of 1-benzyl-2,5-di(thiophen-2-yl)-1H-pyrrole with EDOT Solar Energy Materials and Solar Cells. ,vol. 92, pp. 154- 159 ,(2008) , 10.1016/J.SOLMAT.2006.12.020
I. Kerman, L. Toppare, F. Yilmaz, Y. Yagci, Thiophene Ended ϵ‐Caprolactone Conducting Copolymers and their Electrochromic Properties Journal of Macromolecular Science, Part A. ,vol. 42, pp. 509- 520 ,(2005) , 10.1081/MA-200054363
M. Deepa, Arvind Awadhia, Shweta Bhandari, S.L. Agrawal, Electrochromic performance of a poly(3,4-ethylenedioxythiophene)-Prussian blue device encompassing a free standing proton electrolyte film Electrochimica Acta. ,vol. 53, pp. 7266- 7275 ,(2008) , 10.1016/J.ELECTACTA.2008.04.020
Gorkem E. Gunbas, Pinar Camurlu, İdris Mecidoğlu Akhmedov, Cihangir Tanyeli, Ahmet M. Önal, Levent Toppare, A fast switching, low band gap, p- and n-dopable, donor–acceptor type polymer Journal of Electroanalytical Chemistry. ,vol. 615, pp. 75- 83 ,(2008) , 10.1016/J.JELECHEM.2007.11.035