Transitional current analysis useful for intercalation electrode/solid electrolyte systems

摘要: Abstract We have derived theoretical forms of the transition current to be induced when an electrochemical cell consisting a solid electrolyte and intercalation-type electrode is driven by external source constant voltage, for both cases that kinetics controlled charge transfer diffusion. Experimental data taken with state cell, Li| polymer electrolyte|WO 3 , ITO, are analyzed on these bases. The results demonstrate chrono-amperometric analysis can successfully performed using such without reference electrode.