Direct Experimental Evidence for Reactions between Dissolved Acid Halide and Chlorine Nitrate
作者： J. J. Gilligan , A. W. Castleman
DOI: 10.1021/JP0034978
关键词:
摘要: Cluster chemistry employing a fast flow reactor was used to evaluate the enhanced reactivity of chlorine nitrate (ClONO2) with dissolved acid halide. Reactions ClONO2 deuterium chloride doped deuterated water clusters [D+(D2O)m(DCl)n, (m = 10−14, n 1,2)] were investigated under thermal conditions over temperature range 148−158 K; species employed in place light hydrogen containing molecules facilitate determination reaction mechanisms. Chemical reactions found occur between and only where present. Nitric is remain within cluster yield gaseous (Cl2) from cluster. These results provide direct evidence that an ionic mechanism involved heterogeneous on mimic polar stratospheric cloud surfaces.
harvard.edu
acs.org
sci-hub.se 参考文章(45)
R. J. Shul, B. L. Upschulte, R. Passarella, R. G. Keesee, A. W. Castleman, Thermal Energy Charge-Transfer Reactions of Ar+ and Ar2+ The Journal of Physical Chemistry. ,vol. 91, pp. 2556- 2562 ,(1987) , 10.1021/J100294A022
Kenzo Hiraoka, Susumu Mizuse, Shinichi Yamabe, Solvation of halide ions with water and acetonitrile in the gas phase The Journal of Physical Chemistry. ,vol. 92, pp. 3943- 3952 ,(1988) , 10.1021/J100324A051
L. T. Molina, M. J. Molina, R. A. Stachnik, R. D. Tom, An upper limit to the rate of the hydrogen chloride + ClONO2 reaction The Journal of Physical Chemistry. ,vol. 89, pp. 3779- 3781 ,(1985) , 10.1021/J100264A003
L. C. Anderson, D. W. Fahey, Studies with nitryl hypochlorite: thermal dissociation rate and catalytic conversion to nitric oxide using an NO/O3 chemiluminescence detector The Journal of Physical Chemistry. ,vol. 94, pp. 644- 652 ,(1990) , 10.1021/J100365A027
S. C. Wofsy, M. J. Molina, R. J. Salawitch, L. E. Fox, M. B. McElroy, Interactions between HCl, NOxand H2O ice in the Antarctic stratosphere: Implications for ozone Journal of Geophysical Research. ,vol. 93, pp. 2442- 2450 ,(1988) , 10.1029/JD093ID03P02442
Susan Solomon, Rolando R. Garcia, F. Sherwood Rowland, Donald J. Wuebbles, On the depletion of Antarctic ozone Nature. ,vol. 321, pp. 755- 758 ,(1986) , 10.1038/321755A0
Heather A. Donsig, John C. Vickerman, Dynamic and static secondary ion mass spectrometrystudies of the solvation of HCl by ice Journal of the Chemical Society, Faraday Transactions. ,vol. 93, pp. 2755- 2761 ,(1997) , 10.1039/A701724C
Thomas Schindler, Christian Berg, Gereon Niedner‐Schatteburg, Vladimir E. Bondybey, Heterogeneously catalyzed hydrolysis of chlorine nitrate: Fourier‐transform ion cyclotron resonance investigations of stratospheric chemistry The Journal of Chemical Physics. ,vol. 104, pp. 3998- 4004 ,(1996) , 10.1063/1.471255
Jonathan P McNamara, Gary Tresadern, Ian H Hillier, The facile decomposition of chlorine nitrate in small water clusters Chemical Physics Letters. ,vol. 310, pp. 265- 270 ,(1999) , 10.1016/S0009-2614(99)00762-9
Sally F. Banham, Andrew B. Horn, Thomas G. Koch, John R. Sodeau, Ionisation and solvation of stratospherically relevant molecules on ice films Faraday Discussions. ,vol. 100, pp. 321- 332 ,(1995) , 10.1039/FD9950000321