Effects of Heat Treatment on Photocatalytic Property of Sol-Gel Derived Polycrystalline TiO2

作者: Yoshimi Tanaka , Motohiro Suganuma

DOI: 10.1023/A:1011268421046

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摘要: Polycrystalline TiO2 in the bulk form was prepared by hydrothermal treatment of amorphous gel, and its photocatalytic activity for degradation ethanol physical properties were investigated after drying calcination (300–650°C). The maximum reached when polycrystalline calcinated at temperatures from 300 to 500°C, which almost same as a commercial powder. It markedly reduced above 600°C. Photocatalytic affected crystal growth anatase, progress sintering, anatase-rutile transformation morphology TiO2. characteristic this study that did not vary so much with temperature range 300–500°C.

参考文章(13)
Micha Tomkiewicz, Geula Dagan, Titanium dioxide aerogels for photocatalytic decontamination of aquatic environments The Journal of Physical Chemistry. ,vol. 97, pp. 12651- 12655 ,(1993) , 10.1021/J100151A001
H. Kominami, Y. Takada, H. Yamagiwa, Y. Kera, M. Inoue, T. Inui, Synthesis of thermally stable nanocrystalline anatase by high-temperature hydrolysis of titanium alkoxide with water dissolved in organic solvent from gas phase Journal of Materials Science Letters. ,vol. 15, pp. 197- 200 ,(1996) , 10.1007/BF00274449
Roger I. Bickley, Teresita Gonzalez-Carreno, John S. Lees, Leonardo Palmisano, Richard J.D. Tilley, A structural investigation of titanium dioxide photocatalysts Journal of Solid State Chemistry. ,vol. 92, pp. 178- 190 ,(1991) , 10.1016/0022-4596(91)90255-G
Bulent E. Yoldas, Hydrolysis of titanium alkoxide and effects of hydrolytic polycondensation parameters Journal of Materials Science. ,vol. 21, pp. 1087- 1092 ,(1986) , 10.1007/BF01117399
Geula Dagan, Micha Tomkiewicz, Preparation and characterization of TiO2 aerogels for use as photocatalysts Journal of Non-crystalline Solids. ,vol. 175, pp. 294- 302 ,(1994) , 10.1016/0022-3093(94)90023-X
Kazumi Kato, Photosensitized Oxidation of Ethanol on Alkoxy-Derived TiO2Powders Bulletin of the Chemical Society of Japan. ,vol. 65, pp. 34- 38 ,(1992) , 10.1246/BCSJ.65.34
Sei-ichi Nishimoto, Bunsho Ohtani, Hiroshi Kajiwara, Tsutomu Kagiya, Correlation of the crystal structure of titanium dioxide prepared from titanium tetra-2-propoxide with the photocatalytic activity for redox reactions in aqueous propan-2-ol and silver salt solutions Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. ,vol. 81, pp. 61- 68 ,(1985) , 10.1039/F19858100061
Keiichi Tanaka, Mario F.V. Capule, Teruaki Hisanaga, Effect of crystallinity of TiO2 on its photocatalytic action Chemical Physics Letters. ,vol. 187, pp. 73- 76 ,(1991) , 10.1016/0009-2614(91)90486-S
Bokhimi A. Morales, O. Novaro, T. López, E. Sánchez, R. Gómez, Effect of hydrolysis catalyst on the Ti deficiency and crystallite size of sol-gel-TiO 2 crystalline phases Journal of Materials Research. ,vol. 10, pp. 2788- 2796 ,(1995) , 10.1557/JMR.1995.2788
Scot T. Martin, Colin L. Morrison, Michael R. Hoffmann, Photochemical Mechanism of Size-Quantized Vanadium-Doped TiO2 Particles The Journal of Physical Chemistry. ,vol. 98, pp. 13695- 13704 ,(1994) , 10.1021/J100102A041