Heterogeneous methanation: Steady-state rate of CO hydrogenation on supported ruthenium, nickel and rhenium

作者: R DALLABETTA

DOI: 10.1016/0021-9517(75)90244-4

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摘要: Abstract A study has been made of initial activity, steady-state activity and in the presence H2S for CO hydrogenation on a number supported catalysts. Initial rates were found to be similar Ni Al 2 O 3 , ZrO Raney catalysts when corrected metal surface area. Under conditions, specific reaction rate was factor 25 lower activities order > . In 10 ppm decreased by an additional ⪢ The support appreciable effect extent deactivation at steady state sulfur-containing compounds. addition, comparison Ni, Ru Re streams.

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