Synthesis, characterization and application of carbon nanocages as anode materials for high-performance lithium-ion batteries

作者: Guangda Li , Liqiang Xu , Qin Hao , Meng Wang , Yitai Qian

DOI: 10.1039/C1RA00631B

关键词:

摘要: Carbon nanocages (CNCs) with diameters of about 200∼500 nm have been synthesized by a simple method. The electrochemical properties the CNCs as anode materials were evaluated discharge/charge measurement and impedance spectroscopy. Results showed that displayed excellent cycling performance good rate capability no noticeable capacity fading up to 50 cycles at current densities 100, 300 500 mA g−1. Their significantly improved after annealing treatment 600 °C. For example, CNCs(2)-annealed exhibited much better high reversible 520 mAh g−1 density 100 A discharge 380 can be obtained results Raman, thermal gravimetric analysis indicated graphitization degree, electronic conductivity charge-transfer treatment.

参考文章(45)
H. Zhou, S. Zhu, M. Hibino, I. Honma, M. Ichihara, Lithium Storage in Ordered Mesoporous Carbon (CMK‐3) with High Reversible Specific Energy Capacity and Good Cycling Performance Advanced Materials. ,vol. 15, pp. 2107- 2111 ,(2003) , 10.1002/ADMA.200306125
Brian J. Landi, Matthew J. Ganter, Cory D. Cress, Roberta A. DiLeo, Ryne P. Raffaelle, Carbon nanotubes for lithium ion batteries Energy and Environmental Science. ,vol. 2, pp. 638- 654 ,(2009) , 10.1039/B904116H
Zhi-Min Cui, Ling-Yan Jiang, Wei-Guo Song, Yu-Guo Guo, High-Yield Gas−Liquid Interfacial Synthesis of Highly Dispersed Fe3O4 Nanocrystals and Their Application in Lithium-Ion Batteries Chemistry of Materials. ,vol. 21, pp. 1162- 1166 ,(2009) , 10.1021/CM8033609
Guifu Zou, Dawei Zhang, Chao Dong, Hui Li, Kan Xiong, Linfeng Fei, Yitai Qian, Carbon nanofibers: Synthesis, characterization, and electrochemical properties Carbon. ,vol. 44, pp. 828- 832 ,(2006) , 10.1016/J.CARBON.2005.10.035
David Bom, Rodney Andrews, David Jacques, John Anthony, Bailin Chen, Mark S. Meier, John P. Selegue, Thermogravimetric Analysis of the Oxidation of Multiwalled Carbon Nanotubes: Evidence for the Role of Defect Sites in Carbon Nanotube Chemistry Nano Letters. ,vol. 2, pp. 615- 619 ,(2002) , 10.1021/NL020297U
Jia-Xin Li, Yi Zhao, Lun-Hui Guan, Lithium storage in single-walled carbon nanotubes Electrochemistry Communications. ,vol. 12, pp. 592- 595 ,(2010) , 10.1016/J.ELECOM.2010.02.007
Y. Matsumura, S. Wang, J. Mondori, Mechanism leading to irreversible capacity loss in Li ion rechargeable batteries Journal of The Electrochemical Society. ,vol. 142, pp. 2914- 2918 ,(1995) , 10.1149/1.2048665
Xing-Long Wu, Qiang Liu, Yu-Guo Guo, Wei-Guo Song, Superior storage performance of carbon nanosprings as anode materials for lithium-ion batteries Electrochemistry Communications. ,vol. 11, pp. 1468- 1471 ,(2009) , 10.1016/J.ELECOM.2009.05.033