Tandem Benzylic Oxidation/Dihydroxylation of α-Vinyl- and α-Alkenylbenzyl Alcohols
作者： Rodney A. Fernandes , Pullaiah Kattanguru
关键词:
摘要: A de novo tandem benzylic oxidative dihydroxylation of α-vinyl- and α-alkenylbenzyl alcohols has been developed to give α,β-dihydroxypropiophenones (=2,3-dihydroxy-1-phenylpropan-1-ones) α,β-dihydroxyalkyl phenones. This method was shown be substrate-selective specific for the oxidation alcohols.
sci-hub.se 参考文章(35)
Jiandong Yin, Christina E. Gallis, John D. Chisholm, Tandem Oxidation/Halogenation of Aryl Allylic Alcohols under Moffatt−Swern Conditions Journal of Organic Chemistry. ,vol. 72, pp. 7054- 7057 ,(2007) , 10.1021/JO0711992
Joachim Rudolph, Peter C. Sennhenn, Cornelis P. Vlaar, K. Barry Sharpless, Smaller Substituents on Nitrogen Facilitate the Osmium‐Catalyzed Asymmetric Aminohydroxylation Angewandte Chemie. ,vol. 35, pp. 2810- 2813 ,(1996) , 10.1002/ANIE.199628101
Xin Hao, Tam Nguyen, Daniel B. Kearns, Carolynn C. Arpin, Ray Fall, Tarek Sammakia, New inhibitors of colony spreading in Bacillus subtilis and Bacillus anthracis Bioorganic & Medicinal Chemistry Letters. ,vol. 21, pp. 5583- 5588 ,(2011) , 10.1016/J.BMCL.2011.06.082
John Muldoon, Seth N. Brown, Practical Os/Cu-cocatalyzed air oxidation of allyl and benzyl alcohols at room temperature and atmospheric pressure. Organic Letters. ,vol. 4, pp. 1043- 1045 ,(2002) , 10.1021/OL025648Q
Zhi Wang, Yong-Tao Cui, Zhao-Bing Xu, Jin Qu, Hot water-promoted ring-opening of epoxides and aziridines by water and other nucleopliles. Journal of Organic Chemistry. ,vol. 73, pp. 2270- 2274 ,(2008) , 10.1021/JO702401T
Wei Gong, T. V. RajanBabu, Conformation and reactivity in dibenzocyclooctadienes (DBCOD). A general approach to the total synthesis of fully substituted DBCOD lignans via borostannylative cyclization of α,ω-diynes Chemical Science. ,vol. 4, pp. 3979- 3985 ,(2013) , 10.1039/C3SC51751A
Yuhan Zhou, Thomas Lecourt, Laurent Micouin, Room Temperature Lewis Base-Catalyzed Alumination of Terminal Alkynes Advanced Synthesis & Catalysis. ,vol. 351, pp. 2595- 2598 ,(2009) , 10.1002/ADSC.200900414
Braj B. Lohray, Vidya Bhushan, R. Krishna Kumar, Origin of .alpha.-Hydroxy Ketones in the Osmium Tetroxide-Catalyzed Asymmetric Dihydroxylation of Alkenes Journal of Organic Chemistry. ,vol. 59, pp. 1375- 1380 ,(1994) , 10.1021/JO00085A029
Alice E. Lurain, Patrick J. Carroll, Patrick J. Walsh, One-Pot Asymmetric Synthesis of Acyclic Chiral Epoxy Alcohols via Tandem Vinylation−Epoxidation with Dioxygen Journal of Organic Chemistry. ,vol. 70, pp. 1262- 1268 ,(2005) , 10.1021/JO048345D
Christie Morrill, Robert H. Grubbs, Highly selective 1,3-isomerization of allylic alcohols via rhenium oxo catalysis. Journal of the American Chemical Society. ,vol. 127, pp. 2842- 2843 ,(2005) , 10.1021/JA044054A