Diaminocyclopropenethiones: Synthesis and Reaction Feature

作者: Zen-Ichi Yoshida , Hisatoshi Konishi , Hsanobu Ogoshi

DOI: 10.1002/IJCH.198100030

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摘要: Several diaminocyclopropenethiones (1) are prepared by the reaction of diaminochlorocyclopropenium or triaminocyclopropenium salts with NaSH, and physical properties characterized IR, UV, PMR CMR spectra. Reactions 1 electrophiles afford various diaminothiocyclopropenium salts. Diaminocyclopropenium (10) via oxidizing agents characterized. The effect amino-substituents on cyclopropenium ion is discussed.

参考文章(19)
Z. Yoshida, H. Konishi, Y. Tawara, K. Nishikawa, H. Ogoshi, Novel alkaline hydrolysis of triaminocyclopropenium ion. new route to diaminocyclopropenone and diaminocyclopropenethione Tetrahedron Letters. ,vol. 14, pp. 2619- 2622 ,(1973) , 10.1016/S0040-4039(01)96160-X
Theophil Eicher, Gisela Frenzel, Notizen: Zur Reaktionsweise des Cyclopropenon-Systems. Zeitschrift für Naturforschung B. ,vol. 20, pp. 274- 275 ,(1965) , 10.1515/ZNB-1965-0324
William Esley. Stewart, Thomas H. Siddall, Nuclear magnetic resonance studies of amides Chemical Reviews. ,vol. 70, pp. 517- 551 ,(1970) , 10.1021/CR60267A001
James W. Lown, T. W. Maloney, Diphenylcyclopropenethione S-oxide Journal of Organic Chemistry. ,vol. 35, pp. 1716- 1718 ,(1970) , 10.1021/JO00830A118
Yoshio Kitahara, Makoto Funamizu, Some Derivatives, of 2, 3-Diphenylcyclopropenone Bulletin of the Chemical Society of Japan. ,vol. 37, pp. 1897- 1898 ,(1964) , 10.1246/BCSJ.37.1897
Philip T. S. Lau, M. Kestner, One-step synthesis of 5-hydroxy-1,3-benzoxathiol-2-ones from quinones and thiourea Journal of Organic Chemistry. ,vol. 33, pp. 4426- 4431 ,(1968) , 10.1021/JO01276A025
Sigrid S. Dehmlow, Eckehard V. Dehmlow, Cyclopropenschemie, VI. Cyclopropenone Chemistry, VI. Zeitschrift für Naturforschung B. ,vol. 30, pp. 404- 408 ,(1975) , 10.1515/ZNB-1975-5-620
Ronald. Breslow, John T. Groves, Cyclopropenyl Cation. Synthesis and Characterization Journal of the American Chemical Society. ,vol. 92, pp. 984- 987 ,(1970) , 10.1021/JA00707A040
Milton T. W. Hearn, Kevin T. Potts, Pulse fourier transform 13C nuclear magnetic resonance spectra of cyclopropenones and related derivatives Journal of the Chemical Society, Perkin Transactions 2. ,vol. 6, pp. 1918- 1920 ,(1974) , 10.1039/P29740001918