摘要: The chemistry of the uranyl ion ([UO(2)](2+)) has evolved remarkably over past few years, with unexpected reactivity observed that challenge our understanding this ion, and actinides in general. This review highlights some recent advances field, focussing on organometallic moiety, which is not well developed comparison to lower oxidation states uranium. use as a catalyst highlighted newly supramolecular described. oxygen atoms have been considered inert, but work shown necessarily case discussed herein. Finally, reduction [UO(2)](+) will be discussed.
sci-hub.se 参考文章(155)
C. Madic, B. Guillaume, J.C. Morisseau, J.P. Moulin, “Cation-cation” complexes of pentavalent actinides—I Journal of Inorganic and Nuclear Chemistry. ,vol. 41, pp. 1027- 1031 ,(1979) , 10.1016/0022-1902(79)80082-2
Owen T. Summerscales, F. Geoffrey N. Cloke, Activation of Small Molecules by U(III) Cyclooctatetraene and Pentalene Complexes Structure and Bonding. ,vol. 40, pp. 87- 117 ,(2008) , 10.1007/430_2007_078
Moris S. Eisen, Catalytic C-N, C-O, and C-S Bond Formation Promoted by Organoactinide Complexes ChemInform. ,vol. 42, pp. 157- 184 ,(2010) , 10.1007/978-3-642-12073-2_7
Mareike C. Jahnke, F. Ekkehardt Hahn, Chemistry of N-Heterocyclic Carbene Ligands Transition Metal Complexes of Neutral eta1-Carbon Ligands. ,vol. 30, pp. 95- 129 ,(2010) , 10.1007/978-3-642-04722-0_4
Mark J. Sarsfield, Madeleine Helliwell, David Collison, The first uranyl-methine carbon bond; a complex with out-of-plane uranyl equatorial coordination. Chemical Communications. pp. 2264- 2265 ,(2002) , 10.1039/B206889C
Colm Mallon, Aurora Walshe, Robert J. Forster, Tia E. Keyes, Robert J. Baker, Physical Characterization and Reactivity of the Uranyl Peroxide [UO2(η2-O2)(H2O)2]·2H2O: Implications for Storage of Spent Nuclear Fuels Inorganic Chemistry. ,vol. 51, pp. 8509- 8515 ,(2012) , 10.1021/IC3010823
Mark J. Sarsfield, Helen Steele, Madeleine Helliwell, Simon J. Teat, Uranyl bis-iminophosphorane complexes with in- and out-of-plane equatorial coordinationElectronic supplementary information (ESI) available: Variable temperature 1H NMR spectra; Raman spectra; solid state diffuse reflectance electronic absorption spectra; luminescence spectra; interatomic distances of the optimised structures of 1* and 2* from molecular modelling calculations. See http://www.rsc.org/suppdata/dt/b3/b304602h/ Dalton Transactions. pp. 3443- 3449 ,(2003) , 10.1039/B304602H
Valeria van Axel Castelli, Fernando Bernardi, Antonella Dalla Cort, Luigi Mandolini, Ivan Rossi, Luca Schiaffino, Rates and Equilibria of the Michael-Type Addition of Benzenethiol to 2-Cyclopenten-1-ones. Journal of Organic Chemistry. ,vol. 64, pp. 8122- 8126 ,(1999) , 10.1021/JO9906882
Christopher R. Graves, Jaqueline L. Kiplinger, Pentavalent uranium chemistry: synthetic pursuit of a rare oxidation state. Chemical Communications. pp. 3831- 3853 ,(2009) , 10.1039/B902969A
Grégory Nocton, Pawel Horeglad, Jacques Pécaut, Marinella Mazzanti, Polynuclear cation-cation complexes of pentavalent uranyl: relating stability and magnetic properties to structure. Journal of the American Chemical Society. ,vol. 130, pp. 16633- 16645 ,(2008) , 10.1021/JA804766R