Oscillator Strengths of CF and Comments on Heats of Formation of CF and CF2

作者: Tunis Wentink , Louis Isaacson

DOI: 10.1063/1.1840710

关键词:

摘要: Oscillator strengths (f numbers) and Franck—Condon factors for the A—X B—X band systems of CF are presented. Separate results CF(A—X) based on directly measured radiative lifetimes shock‐tube intensities compared. These data indicate that heat formation CF2 especially may be significantly different from accepted JANAF table values.

参考文章(11)
Daniel R. Stull, JANAF thermochemical tables 堀越研究所. ,(1966)
J. A. Harrington, A. P. Modica, D. R. Libby, Shock‐Tube Determination of the C2(A3Π→X3Π) and CF(A2Σ+→X2Π) Band‐System Oscillator Strengths Journal of Chemical Physics. ,vol. 44, pp. 3380- 3387 ,(1966) , 10.1063/1.1727241
D.J. Flinn, R.J. Spindler, S. Fifer, M. Kelly, Franck-Condon factors for the β and γ bands of the NO molecule based on realistic potential functions Journal of Quantitative Spectroscopy and Radiative Transfer. ,vol. 4, pp. 271- 282 ,(1964) , 10.1016/0022-4073(64)90070-6
B. A. Thrush, J. J. Zwolenik, Predissociation in the absorption spectra of CF and CF2 Transactions of the Faraday Society. ,vol. 59, pp. 582- 587 ,(1963) , 10.1039/TF9635900582
Robert S. Mulliken, Intensities of Electronic Transitions in Molecular Spectra I. Introduction Journal of Chemical Physics. ,vol. 7, pp. 14- 20 ,(1939) , 10.1063/1.1750317
E B Andrews, R F Barrow, The Band-Spectrum of Carbon Monofluoride, CF Proceedings of the Physical Society. Section A. ,vol. 64, pp. 481- 492 ,(1951) , 10.1088/0370-1298/64/5/307
James E. Hesser, Kurt Dressler, Radiative Lifetimes of Ultraviolet Molecular Transitions The Journal of Chemical Physics. ,vol. 45, pp. 3149- 3150 ,(1966) , 10.1063/1.1728073
J. A. Harrington, A. P. Modica, D. R. Libby, Erratum: Shock‐Tube Determination of the C2(A 3II→X 3II) and CF(A 2Σ+→X 2II) Band‐System Oscillator Strengths The Journal of Chemical Physics. ,vol. 45, pp. 2720- 2720 ,(1966) , 10.1063/1.1728014
A. P. Modica, Kinetics and Equilibria of the Difluorocarbene Radical Decomposition Behind Shock Waves Journal of Chemical Physics. ,vol. 44, pp. 1585- 1589 ,(1966) , 10.1063/1.1726895
Robert J. Spindler, Franck-Condon factors based on RKR potentials with applications to radiative absorption coefficients Journal of Quantitative Spectroscopy and Radiative Transfer. ,vol. 5, pp. 165- 204 ,(1965) , 10.1016/0022-4073(65)90039-7