Evaluation of structural, spectral, thermal and optical properties of an efficient centrosymmetric organic single crystal 2-[2-(4-diethylamino-phenyl)-vinyl]-1-methyl pyridinium tetrafluoroborate for nonlinear optical applications

作者: K. Nivetha , K. Aravinth , K. Senthil , S. Kalainathan

DOI: 10.1016/J.MOLSTRUC.2020.129082

关键词:

摘要: In the present work, a novel ᴨ-conjugated stilbazolium chromophore of 2-[2-(4-diethylamino-phenyl)-vinyl]-1-methyl pyridinium tetrafluoroborate (DESTB) has been synthesized and grown by slow solvent evaporation technique. Single crystal X-ray diffraction demonstrates that DESTB crystallizes in centrosymmetric monoclinic system with the space group P2 1/C. The different vibrational modes of DESTB were confirmed by Fourier transform infrared analysis. The thermal properties of DESTB sample were analyzed using TG/DTA …

参考文章(44)
F. Pan, G. Knöpfle, Ch. Bosshard, S. Follonier, R. Spreiter, M. S. Wong, P. Günter, Electro‐optic properties of the organic salt 4‐N,N‐dimethylamino‐4′‐N′‐methyl‐stilbazolium tosylate Applied Physics Letters. ,vol. 69, pp. 13- 15 ,(1996) , 10.1063/1.118101
Zainab S Sadik, Dhia H Al-Amiedy, Amal F Jaffar, Third Order Optical Nonlinearities of C 450 Doped Polymer Thin Film Investigated by the Z-Scan Advances in Materials Physics and Chemistry. ,vol. 2, pp. 43- 49 ,(2012) , 10.4236/AMPC.2012.21007
Wenfang Sun, Chris M. Lawson, Gary M. Gray, Chuanlang Zhan, Duoyuan Wang, Degenerate four-wave mixing and Z-scan measurements of stilbazolium derivatives Applied Physics Letters. ,vol. 78, pp. 1817- 1819 ,(2001) , 10.1063/1.1355293
Pil-Joo Kim, Mojca Jazbinsek, Jae-Hyeok Jeong, Jong-Taek Kim, Yoon Sup Lee, Yeong-Min Jung, Soon W. Lee, O-Pil Kwon, New acentric quinolinium crystal with high order parameter for nonlinear optical and electro-optic applications CrystEngComm. ,vol. 14, pp. 3633- 3637 ,(2012) , 10.1039/C2CE06667J
Arno Schneider, Ivan Biaggio, Peter Günter, Terahertz-induced lensing and its use for the detection of terahertz pulses in a birefringent crystal Applied Physics Letters. ,vol. 84, pp. 2229- 2231 ,(2004) , 10.1063/1.1688986
M. Krishna Kumar, S. Sudhahar, A. Silambarasan, B.M. Sornamurthy, R. Mohan Kumar, Crystal growth, structural, linear and nonlinear optical studies of 4-methyl-4′-N’-methylstilbazolium tosylate single crystals Optik. ,vol. 125, pp. 751- 755 ,(2014) , 10.1016/J.IJLEO.2013.07.040
J. L. Bredas, C. Adant, P. Tackx, A. Persoons, B. M. Pierce, THIRD-ORDER NONLINEAR OPTICAL RESPONSE IN ORGANIC MATERIALS : THEORETICAL AND EXPERIMENTAL ASPECTS Chemical Reviews. ,vol. 94, pp. 243- 278 ,(1994) , 10.1021/CR00025A008