Furans in synthesis.7. A formal total synthesis of (+/−)-perhydrohistrionicotoxin

作者: Steven P Tanis , Lisa A Dixon

DOI: 10.1016/S0040-4039(00)95450-9

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摘要: Abstract A formal total synthesis of (+/−)-perhydrohistrionicotoxin is reported. This sequence utilizes a regiospecific N -acyliminium ion initiated-furan terminated cyclization to construct the desired azaspiro[5.5]undecane ring system.

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