Dendronized Polymers with Aromatic Sulfonimide Dendrons
作者： Mona Ahmed Abdel-Rahman , Bernd W. Schweizer , Oleg Lukin , Afang Zhang , A. Dieter Schlüter
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摘要: The synthesis of high-molar-mass first- and second-generation, aromatic sulfonamide-based dendronized polymers PG1(CH 3 ) PG1(NO 2 as well PG2(CH PG2(NO has been achieved. For PG3(CH at least oligomeric material could be obtained. exhibit glass transition temperatures in the range 135-162°C are valuable components for a presently ongoing depth analysis persistence length by SANS. corresponding monomers MG2(CH MG2(NO were crystallized their structures crystal determined XRD. These single crystals first ever obtained dendritic macromonomers. polymerizable units found not to proper spatial relation allow solid-state polymerization.
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