Pt-Based Icosahedral Nanocages: Using a Combination of {111} Facets, Twin Defects, and Ultrathin Walls to Greatly Enhance Their Activity toward Oxygen Reduction

作者: Xue Wang , Legna Figueroa-Cosme , Xuan Yang , Ming Luo , Jingyue Liu

DOI: 10.1021/ACS.NANOLETT.5B05140

关键词:

摘要: Engineering the surface structure of noble-metal nanocrystals offers an effective route to the development of catalysts or electrocatalysts with greatly enhanced activity. Here, we report …

参考文章(30)
Jinho Park, Lei Zhang, Sang-Il Choi, Luke T. Roling, Ning Lu, Jeffrey A. Herron, Shuifen Xie, Jinguo Wang, Moon J. Kim, Manos Mavrikakis, Younan Xia, Atomic layer-by-layer deposition of platinum on palladium octahedra for enhanced catalysts toward the oxygen reduction reaction. ACS Nano. ,vol. 9, pp. 2635- 2647 ,(2015) , 10.1021/NN506387W
Jun Zhang, Hongzhou Yang, Jiye Fang, Shouzhong Zou, Synthesis and Oxygen Reduction Activity of Shape-Controlled Pt3Ni Nanopolyhedra Nano Letters. ,vol. 10, pp. 638- 644 ,(2010) , 10.1021/NL903717Z
Yijin Kang, Jun Beom Pyo, Xingchen Ye, Rosa E. Diaz, Thomas R. Gordon, Eric A. Stach, Christopher B. Murray, Shape-controlled synthesis of Pt nanocrystals: the role of metal carbonyls. ACS Nano. ,vol. 7, pp. 645- 653 ,(2013) , 10.1021/NN3048439
Taekyung Yu, Do Youb Kim, Hui Zhang, Younan Xia, Platinum concave nanocubes with high-index facets and their enhanced activity for oxygen reduction reaction. Angewandte Chemie. ,vol. 50, pp. 2773- 2777 ,(2011) , 10.1002/ANIE.201007859
Tian Lv, Yi Wang, Sang-Il Choi, Miaofang Chi, Jing Tao, Likun Pan, Cheng Zhi Huang, Yimei Zhu, Younan Xia, Controlled Synthesis of Nanosized Palladium icosahedra and Their Catalytic Activity towards Formic‐Acid Oxidation Chemsuschem. ,vol. 6, pp. 1923- 1930 ,(2013) , 10.1002/CSSC.201300479
V. R. Stamenkovic, B. Fowler, B. S. Mun, G. Wang, P. N. Ross, C. A. Lucas, N. M. Markovic, Improved Oxygen Reduction Activity on Pt3Ni(111) via Increased Surface Site Availability Science. ,vol. 315, pp. 493- 497 ,(2007) , 10.1126/SCIENCE.1135941
Shuifen Xie, Ning Lu, Zhaoxiong Xie, Jinguo Wang, Moon J. Kim, Younan Xia, Synthesis of Pd-Rh core-frame concave nanocubes and their conversion to Rh cubic nanoframes by selective etching of the Pd cores. Angewandte Chemie. ,vol. 51, pp. 10266- 10270 ,(2012) , 10.1002/ANIE.201206044
Yujie Xiong, Jingyi Chen, Benjamin Wiley, Younan Xia, Yadong Yin, Zhi-Yuan Li, Size-dependence of surface plasmon resonance and oxidation for Pd nanocubes synthesized via a seed etching process. Nano Letters. ,vol. 5, pp. 1237- 1242 ,(2005) , 10.1021/NL0508826
Chao Wang, Hideo Daimon, Taigo Onodera, Tetsunori Koda, Shouheng Sun, A general approach to the size- and shape-controlled synthesis of platinum nanoparticles and their catalytic reduction of oxygen. Angewandte Chemie. ,vol. 47, pp. 3588- 3591 ,(2008) , 10.1002/ANIE.200800073
Rod Borup, Jeremy Meyers, Bryan Pivovar, Yu Seung Kim, Rangachary Mukundan, Nancy Garland, Deborah Myers, Mahlon Wilson, Fernando Garzon, David Wood, Piotr Zelenay, Karren More, Ken Stroh, Tom Zawodzinski, James Boncella, James E. McGrath, Minoru Inaba, Kenji Miyatake, Michio Hori, Kenichiro Ota, Zempachi Ogumi, Seizo Miyata, Atsushi Nishikata, Zyun Siroma, Yoshiharu Uchimoto, Kazuaki Yasuda, Ken-ichi Kimijima, Norio Iwashita, Scientific aspects of polymer electrolyte fuel cell durability and degradation. Chemical Reviews. ,vol. 107, pp. 3904- 3951 ,(2007) , 10.1021/CR050182L