A complete 1H and 13C NMR data assignment for four drimane sesquiterpenoids isolated from Drimys winterii.

作者: Benjamín Rodríguez , Nelson Zapata , Pilar Medina , Elisa Viñuela

DOI: 10.1002/MRC.1500

关键词:

摘要: From the bark of Drimys winterii Forst., drimane derivatives drimendiol, polygodial, isotadeonal and isodrimeninol were isolated. Complete unambiguous 1H 13C NMR chemical shift assignments these compounds achieved by COSY experiments, 13C/1H correlation diagrams NOE experiments. Isotadeonal found for first time in this plant species. Copyright © 2004 John Wiley & Sons, Ltd.

参考文章(22)
H. H. Appel, C. J. W. Brooks, K. H. Overton, 673. The constitution and stereochemistry of drimenol, a novel bicyclic sesquiterpenoid Journal of The Chemical Society (resumed). pp. 3322- 3332 ,(1959) , 10.1039/JR9590003322
P. M. Imamura, P. C. M. L. Miranda, R. A. Giacomini, A complete 1H and 13C NMR data assignment for the diterpene methyl (−)-zanzibarate by 2D spectroscopy and NOE experiments Magnetic Resonance in Chemistry. ,vol. 42, pp. 561- 563 ,(2004) , 10.1002/MRC.1379
Manuel Cortés, Luis Moreno, José López, None, Partial Synthesis of (–)-11,12-Dinordriman-8-one and the (–)-Enantiomer of Polywood† Journal of Chemical Research-s. pp. 36- 37 ,(1998) , 10.1039/A702743E
Geoffrey D. Brown, Drimendiol, a sesquiterpene from Drymis winterii Phytochemistry. ,vol. 35, pp. 975- 977 ,(1994) , 10.1016/S0031-9422(00)90650-2
P.J. Houghton, J. Manby, Medicinal plants of the Mapuche. Journal of Ethnopharmacology. ,vol. 13, pp. 89- 103 ,(1985) , 10.1016/0378-8741(85)90063-7
Gérard Aranda, Isabelle Facon, Jean-Yves Lallemand, Massoumée Leclaire, Robert Azerad, Manuel Cortes, Jose Lopez, Hector Ramirez, Microbiological hydroxylation in the drimane series Tetrahedron Letters. ,vol. 33, pp. 7845- 7848 ,(1992) , 10.1016/S0040-4039(00)74759-9
H. H. Appel, J. D. Connolly, K. H. Overton, R. P. M. Bond, 906. Sesquiterpenoids. Part II. The constitution and stereochemistry of drimenin, isodrimenin, and confertifolin Journal of The Chemical Society (resumed). pp. 4685- 4692 ,(1960) , 10.1039/JR9600004685
Geoffrey D. Brown, The sesquiterpenes of Fabiana imbricata Phytochemistry. ,vol. 35, pp. 425- 433 ,(1994) , 10.1016/S0031-9422(00)94775-7