A wide pH range optical sensing system based on a sol–gel encapsulated amino-functionalised corrole
作者： Chun-Yan Li , Xiao-Bing Zhang , Zhi-Xiang Han , Björn Åkermark , Licheng Sun
DOI: 10.1039/B514510D
关键词:
摘要: The synthesis of a new compound, 10-(4-aminophenyl)-5,15-dimesitylcorrole, and its application for the preparation optical chemical pH sensors is described. dye materials were immobilized in sol–gel glass matrix characterised upon exposure to aqueous buffer solutions. response sensor based on fluorescence intensity changing corrole owing multiple steps protonation deprotonation. Due containing several proton sensitive centers, 10-(4-aminophenyl)-5,15-dimesitylcorrole optode shows wider range toward than that tetraphenylporphyrin (TPPH2) 5,10,15-tris(pentafluorophenyl)corrole (H3(tpfc)). It linear 2.17–10.30. effect composition membrane has been studied experimental conditions optimized. showed good reproducibility reversibility, common co-existing inorganic ions did not show obvious interference measurement.
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S. Brasselet, W.E. Moerner, Fluorescence Behavior of Single‐Molecule pH‐Sensors Single Molecules. ,vol. 1, pp. 17- 23 ,(2000) , 10.1002/(SICI)1438-5171(200004)1:1<17::AID-SIMO17>3.0.CO;2-E
Ernö Lindner, Vasile V. Cosofret, Robert P. Kusy, Richard P. Buck, Thomas Rosatzin, Ulrich Schaller, Wilhelm Simon, Judit Jeney, Klára Tóth, Ernö Pungor, Responses of H(+) selective solvent polymeric membrane electrodes fabricated from modified PVC membranes. Talanta. ,vol. 40, pp. 957- 967 ,(1993) , 10.1016/0039-9140(93)80151-G
Vasile V. Cosofret, Tal M. Nahir, Ernö Lindner, Richard P. Buck, New neutral carrier-based H+ selective membrane electrodes Journal of Electroanalytical Chemistry. ,vol. 327, pp. 137- 146 ,(1992) , 10.1016/0022-0728(92)80142-Q
Aleksandra Lobnik, Ines Oehme, Ivana Murkovic, Otto S Wolfbeis, pH optical sensors based on sol–gels: Chemical doping versus covalent immobilization Analytica Chimica Acta. ,vol. 367, pp. 159- 165 ,(1998) , 10.1016/S0003-2670(97)00708-3
Delana A Nivens, Yunke Zhang, S.Michael Angel, A fiber-optic pH sensor prepared using a base-catalyzed organo-silica sol–gel Analytica Chimica Acta. ,vol. 376, pp. 235- 245 ,(1998) , 10.1016/S0003-2670(98)00505-4
Darrell R Fry, Donald R Bobbitt, Investigation of dynamically modified optical-fiber sensors for pH sensing at the extremes of the pH scale Microchemical Journal. ,vol. 69, pp. 25- 33 ,(2001) , 10.1016/S0026-265X(00)00191-0
Daniel T. Gryko, Katarzyna Jadach, A simple and versatile one-pot synthesis of meso-substituted trans-A2B-corroles. Journal of Organic Chemistry. ,vol. 66, pp. 4267- 4275 ,(2001) , 10.1021/JO010146W
Zeev Gross, Galina Golubkov, Liliya Simkhovich, Epoxidation Catalysis by a Manganese Corrole and Isolation of an Oxomanganese(V) Corrole Angewandte Chemie. ,vol. 39, pp. 4045- 4047 ,(2000) , 10.1002/1521-3773(20001117)39:22<4045::AID-ANIE4045>3.0.CO;2-P
Chang-Hee Lee, Jonathan S. Lindsey, One-flask synthesis of meso-substituted dipyrromethanes and their application in the synthesis of trans-substituted porphyrin building blocks Tetrahedron. ,vol. 50, pp. 11427- 11440 ,(1994) , 10.1016/S0040-4020(01)89282-6
S. C. Ma, N. A. Chaniotakis, Mark E. Meyerhoff, Response properties of ion-selective polymeric membrane electrodes prepared with aminated and carboxylated poly(vinyl chloride). Analytical Chemistry. ,vol. 60, pp. 2293- 2299 ,(1988) , 10.1021/AC00171A027