Vapor pressures, liquid molar volumes, vapor non-idealities, and critical properties of some fluorinated ethers: CF3OCF2OCF3, CF3OCF2CF2H, c-CF2CF2CF2O, CF3OCF2H, and CF3OCH3; and of CCI3F and CF2CIH

作者: Bao-Huai Wang , James L. Adcock , Shyam B. Mathur , W. Alexander van Hook

DOI: 10.1016/S0021-9614(05)80208-3

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摘要: Vapor pressures, compressibilities, expansivities, and molar volumes of the liquid phase have been measured between room temperature critical for a series fluorinated ethers: CF 3 OCF 2 , H, c -CF O, OCH . Vapor-phase non-idealities were each compound, but only samples high vapor density. Critical temperatures pressures approximate melting boiling are reported. Apparatus calibrations checked with measurements on well characterized materials: CFCl (R11) ClH (R22).

参考文章(21)
John Shipley Rowlinson, Liquids and liquid mixtures ,(1959)
Walter Kauzmann, David S. Eisenberg, The Structure and Properties of Water ,(1969)
Raja F. Hajjar, George E. MacWood, Second Virial Coefficients and the Force Constants, ε0 and r0, of Six Halogen‐Substituted Methanes Journal of Chemical Physics. ,vol. 49, pp. 4567- 4570 ,(1968) , 10.1063/1.1669914
S. Matsuo, A. Van Hook, Isothermal compressibility of C6H6, C6D6, c-C6D12, and their mixtures from 0.1 to 35 MPa at 288, 298, and 313 K The Journal of Physical Chemistry. ,vol. 88, pp. 1032- 1040 ,(1984)
A. P. Kudchadker, S. A. Kudchadker, R. P. Shukla, P. R. Patnaik, Vapor Pressures and Boiling Points of Selected Halomethanes Journal of Physical and Chemical Reference Data. ,vol. 8, pp. 499- 517 ,(1979) , 10.1063/1.555600
James L. Adcock, Sastry A. Kunda, Donald R. Taylor, Mario J. Nappa, Allen C. Sievert, Aerosol direct fluorination of C1 and C2 chlorocarbons Industrial & Engineering Chemistry Research. ,vol. 28, pp. 1547- 1549 ,(1989) , 10.1021/IE00094A019