Chemodosimeters and 3D inorganic functionalised hosts for the fluoro-chromogenic sensing of anions

作者: Ramón Martínez-Máñez , Félix Sancenón

DOI: 10.1016/J.CCR.2006.04.016

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摘要: Abstract We report here recent examples developed in our research group on the development of novel chemodosimeters for fluoro-chromogenic anion sensing. For instance, squaridine, pyrylium and pent-2-en-1,5-dione dye scaffoldings have been used to obtain highly specific chromo-fluorogenic responses anions such as cyanide, sulfide or certain carboxylates water mixed aqueous solutions. will also new use “smart sensory materials” based nanoscopic inorganic structures bio-mimetic hosts These systems combine molecular ideas 3D solid pre-organised features design concepts organic/inorganic hybrid materials recognition/sensing protocols. functionalisation siliceous mesoporous with ureas, thioureas, guanidinium groups saccharides suitable dyes has resulted enhanced sensing anionic species fatty acids, citrate borate.

参考文章(63)
Jamal El Haskouri, David Ortiz de Zárate, Carmen Guillem, Julio Latorre, Maite Caldés, Aurelio Beltrán, Daniel Beltrán, Ana B. Descalzo, Gertrudis Rodríguez-López, Ramón Martínez-Máñez, M. Dolores Marcos, Pedro Amorós, Silica-based powders and monoliths with bimodal pore systems Chemical Communications. pp. 330- 331 ,(2002) , 10.1039/B110883B
Ana B. Descalzo, Diego Jiménez, Jamal El Haskouri, Daniel Beltrán, Pedro Amorós, M. Dolores Marcos, Ramón Martínez-Máñez, Juan Soto, A new method for fluoride determination by using fluorophores and dyes anchored onto MCM-41 Chemical Communications. pp. 562- 563 ,(2002) , 10.1039/B111128K
Yeon-Hwan Kim, Jong-In Hong, Ion pair recognition by Zn–porphyrin/crown ether conjugates: visible sensing of sodium cyanide Chemical Communications. pp. 512- 513 ,(2002) , 10.1039/B109596J
Pavel Anzenbacher,, Daniel S. Tyson, Karolina Jursíková, Felix N. Castellano, Luminescence lifetime-based sensor for cyanide and related anions. Journal of the American Chemical Society. ,vol. 124, pp. 6232- 6233 ,(2002) , 10.1021/JA0259180
Harold C. Hodge, Marion N. Gleason, Robert E. Gosselin, Clinical Toxicology of Commercial Products ,(1969)
Paul D. Beer, Elizabeth J. Hayes, Transition metal and organometallic anion complexation agents Coordination Chemistry Reviews. ,vol. 240, pp. 167- 189 ,(2003) , 10.1016/S0010-8545(02)00303-X
Mi Young Chae, Anthony W. Czarnik, Fluorimetric chemodosimetry. Mercury(II) and silver(I) indication in water via enhanced fluorescence signaling Journal of the American Chemical Society. ,vol. 114, pp. 9704- 9705 ,(1992) , 10.1021/JA00050A085
Marco Montalti, Luca Prodi, Nelsi Zaccheroni, Giuseppe Falini, Solvent-induced modulation of collective photophysical processes in fluorescent silica nanoparticles. Journal of the American Chemical Society. ,vol. 124, pp. 13540- 13546 ,(2002) , 10.1021/JA027270X
Jose V. Ros-Lis, Ramón Martínez-Máñez, Knut Rurack, Félix Sancenón, Juan Soto, Monika Spieles, Highly selective chromogenic signaling of Hg2+ in aqueous media at nanomolar levels employing a squaraine-based reporter. Inorganic Chemistry. ,vol. 43, pp. 5183- 5185 ,(2004) , 10.1021/IC049422Q
Ana B. Descalzo, Knut Rurack, Hardy Weisshoff, Ramón Martínez-Máñez, M. Dolores Marcos, Pedro Amorós, Katrin Hoffmann, Juan Soto, Rational design of a chromo- and fluorogenic hybrid chemosensor material for the detection of long-chain carboxylates. Journal of the American Chemical Society. ,vol. 127, pp. 184- 200 ,(2005) , 10.1021/JA045683N