Green synthesis of copper nanoparticles using aqueous extract of the leaves of Euphorbia esula L and their catalytic activity for ligand-free Ullmann-coupling reaction and reduction of 4-nitrophenol

作者: Mahmoud Nasrollahzadeh , S. Mohammad Sajadi , Mehdi Khalaj

DOI: 10.1039/C4RA08863H

关键词:

摘要: This paper reports on the biosynthesis of copper nanoparticles (NPs) using extract Euphorbia esula L leaves as reductant and stabilizer without any surfactant. The catalytic efficiency prepared Cu NPs for reduction 4-nitrophenol ligand-free Ullmann-coupling reaction is discussed. were characterized with UV-vis, XRD TEM methods. method has advantages high yields, simple methodology, elimination ligand easy work up.

参考文章(28)
F Halaweish, S Kronberg, JA Rice, Rodent and ruminant ingestive response to flavonoids in Euphorbia esula. Journal of Chemical Ecology. ,vol. 29, pp. 1073- 1082 ,(2003) , 10.1023/A:1023869220586
Hildebert Wagner, Heinz Danninger, Otto Seligmann, Mihaly Nogradi, Lorand Farkas, Norman Farnsworth, Synthese von Glucuroniden der Flavonoid-Reihe, II. Isolierung von Kämpferol-3-β-D-glucuronid ausEuphorbia esula L. und seine Synthese Chemische Berichte. ,vol. 103, pp. 3678- 3683 ,(1970) , 10.1002/CBER.19701031132
Mahmoud Nasrollahzadeh, Mehdi Maham, Mohammad Mostafa Tohidi, Green synthesis of water-dispersable palladium nanoparticles and their catalytic application in the ligand- and copper-free Sonogashira coupling reaction under aerobic conditions Journal of Molecular Catalysis A: Chemical. ,vol. 391, pp. 83- 87 ,(2014) , 10.1016/J.MOLCATA.2014.04.004
Mahmoud Nasrollahzadeh, Abbas Azarian, Ali Ehsani, Mehdi Khalaj, Preparation, optical properties and catalytic activity of TiO 2 @Pd nanoparticles as heterogeneous and reusable catalysts for ligand-free Heck coupling reaction Journal of Molecular Catalysis A: Chemical. ,vol. 394, pp. 205- 210 ,(2014) , 10.1016/J.MOLCATA.2014.06.033
Faysal Benaskar, Volker Engels, Narendra Patil, Evgeny V. Rebrov, Jan Meuldijk, Volker Hessel, Lumbertus A. Hulshof, David A. Jefferson, Jaap. C. Schouten, Andrew E.H. Wheatley, Copper(0) in the Ullmann heterocycle-aryl ether synthesis of 4-phenoxypyridine using multimode microwave heating Tetrahedron Letters. ,vol. 51, pp. 248- 251 ,(2010) , 10.1016/J.TETLET.2009.10.126
Davood Habibi, Mahmoud Nasrollahzadeh, Hesam Sahebekhtiari, Green synthesis of formamides using the Natrolite zeolite as a natural, efficient and recyclable catalyst Journal of Molecular Catalysis A-chemical. ,vol. 378, pp. 148- 155 ,(2013) , 10.1016/J.MOLCATA.2013.04.001