One-step synthesis of methyl isobutyl ketone from acetone with calcined Mg/Al hydrotalcite-supported palladium or nickel catalysts
作者： Y.Z Chen , C.M Hwang , C.W Liaw
DOI: 10.1016/S0926-860X(98)00019-2
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摘要: Abstract Calcined Mg/Al hydrotalcites (CHT) with various atomic ratios of were prepared and used as support. One-step synthesis methyl isobutyl ketone (MIBK) from acetone hydrogen at atmospheric pressure was investigated over Pd/CHT Ni/CHT catalysts. These catalysts showed high activities selectivities to MIBK, reaching 60–70% selectivity 35–40% conversion in some experiments. A temperature ca. 140°C sufficiently for the calcined hydrotalcite-supported catalyst assume basic properties good MIBK synthesis. The loading metal (or density sites) an important factor product distribution strong metal–support interaction exhibited these higher reduction (>500°C) needed considerable reactivity selectivities. played role behavior
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sci-hub.se 参考文章(13)
W REICHLE, Pulse microreactor examination of the vapor-phase aldol condensation of acetone Journal of Catalysis. ,vol. 63, pp. 295- 306 ,(1980) , 10.1016/0021-9517(80)90082-2
Geng Zhang, Hideshi Hattori, Kozo Tanabe, Aldol Addition of Acetone, Catalyzed by Solid Base Catalysts: Magnesium Oxide, Calcium Oxide, Strontium Oxide, Barium Oxide, Lanthanum (III) Oxide and Zirconium Oxide Applied Catalysis. ,vol. 36, pp. 189- 197 ,(1988) , 10.1016/S0166-9834(00)80114-1
Yasuhiko Higashio, Toshio Nakayama, One-step synthesis of methyl isobutyl ketone catalyzed by palladium supported on niobic acid Catalysis Today. ,vol. 28, pp. 127- 131 ,(1996) , 10.1016/0920-5861(95)00219-7
Luis M. Gandía, Robin Malm, Roger Marchand, Roland Conanec, Yves Laurent, Mario Montes, Application of a new hydrogenated aluminophosphate oxynitride (ALPON) as a catalytic support for the one-step synthesis of methyl isobutyl ketone from acetone Applied Catalysis A-general. ,vol. 114, ,(1994) , 10.1016/0926-860X(94)85105-0
Andrew L McKenzie, Christopher T Fishel, Robert J Davis, Investigation of the surface structure and basic properties of calcined hydrotalcites Journal of Catalysis. ,vol. 138, pp. 547- 561 ,(1992) , 10.1016/0021-9517(92)90306-3
F. Cavani, F. Trifirò, A. Vaccari, Hydrotalcite-type anionic clays: Preparation, properties and applications. Catalysis Today. ,vol. 11, pp. 173- 301 ,(1991) , 10.1016/0920-5861(91)80068-K
W REICHLE, The nature of the thermal decomposition of a catalytically active anionic clay mineral Journal of Catalysis. ,vol. 101, pp. 352- 359 ,(1986) , 10.1016/0021-9517(86)90262-9
Luis M. Gandía, Mario Montes, Highly selective one-step formation of methyl isobutyl ketone from acetone with a magnesia supported nickel catalyst Applied Catalysis A: General. ,vol. 101, pp. L1- L6 ,(1993) , 10.1016/0926-860X(93)80132-A
Fernando Rey, Vicente Fornés, José M. Rojo, Thermal decomposition of hydrotalcites. An infrared and nuclear magnetic resonance spectroscopic study Journal of the Chemical Society, Faraday Transactions. ,vol. 88, pp. 2233- 2238 ,(1992) , 10.1039/FT9928802233
Shigeo Miyata, Anion-Exchange Properties of Hydrotalcite-Like Compounds Clays and Clay Minerals. ,vol. 31, pp. 305- 311 ,(1983) , 10.1346/CCMN.1983.0310409