Mass spectra of chlorinated aromatics formed in pulp bleaching: I—chlorinated catechols

作者: Juha Knuutinen , Ilpo O. O. Korhonen

DOI: 10.1002/OMS.1210181007

关键词:

摘要: The fragmentation of chlorinated guaiacols (2-methoxyphenols) on electron impact has been studied. most common processes are interpreted and in some cases the small differences between spectra positional isomers explained. In addition to well-known alkyl-oxygen fission (loss methyl radical), metastable ion studies deuterium labelling have indicated several new pathways. characteristic formation [MCH3HCl]+ [MCH3Cl]+· ions. general, however, shown be very similar.

参考文章(14)
J. Knuutinen, E. Kolehmainen, Gas chromatographic study of acetyl derivates of chlorinated guaiacols Chromatographia. ,vol. 15, pp. 707- 711 ,(1982) , 10.1007/BF02261890
Vladimír Kováčik, Ján Škamla, Dušan Joniak, Božena Košíková, Massenspektrometrie einiger Modellsubstanzen des Lignins, I Chemische Berichte. ,vol. 102, pp. 1513- 1522 ,(1969) , 10.1002/CBER.19691020512
Thomas. Aczel, H. E. Lumpkin, Correlation of mass spectra with structure in aromatic oxygenated compounds.Aromatic alcohols and phenols Analytical Chemistry. ,vol. 32, pp. 1819- 1822 ,(1960) , 10.1021/AC50153A035
J. Knuutinen, J. Tarhanen, M. Lahtiperä, Gas chromatographic and mass spectrometric analysis of chlorinated catechols occurring in pulp bleach liquors Chromatographia. ,vol. 15, pp. 9- 12 ,(1982) , 10.1007/BF02269031
J. Knuutinen, Thin-layer chromatography of chlorinated catechols on a silica gel 60 layer Journal of Chromatography A. ,vol. 209, pp. 446- 450 ,(1981) , 10.1016/S0021-9673(00)80614-7
J. Knuutinen, Analysis of chlorianted guaiacols in spent bleac liquor from a pulp mill Journal of Chromatography A. ,vol. 248, pp. 289- 295 ,(1982) , 10.1016/S0021-9673(00)87280-5
CS Barnes, JL Occolowitz, The Mass Spectra of Phenyl Methyl Ethers Australian Journal of Chemistry. ,vol. 16, pp. 219- 224 ,(1963) , 10.1071/CH9630219
Krister Lindström, Jan Nordin, Gas chromatography-mass spectrometry of chlorophenols in spent bleach liquors Journal of Chromatography A. ,vol. 128, pp. 13- 26 ,(1976) , 10.1016/S0021-9673(00)84026-1
Lars Renberg, Krister Lindström, C18 reversed-phase trace enrichment of chlorinated phenols, guaiacols and catechols in water Journal of Chromatography A. ,vol. 214, pp. 327- 334 ,(1981) , 10.1016/S0021-9673(00)80561-0
Itshak Granoth, ortho-Effect in some aromatic ethers, sulphides, and sulphoxides under electron impact Journal of The Chemical Society-perkin Transactions 1. pp. 1503- 1505 ,(1972) , 10.1039/P29720001503