Critical assessment of steady-state kinetic models for the synthesis of methanol over an industrial Cu/ZnO/Al2O3 catalyst
作者： Y. Slotboom , M.J. Bos , J. Pieper , V. Vrieswijk , B. Likozar
DOI: 10.1016/J.CEJ.2020.124181
关键词:
摘要: … This physically consistent model has ten parameters, however more experiments are needed, because the current dataset is not discriminating enough for regression of adsorption …
utwente.nl
mendeley.com
elsevier.com参考文章(48)
Y. Choi, K. Futagami, T. Fujitani, J. Nakamura, The difference in the active sites for CO2 and CO hydrogenations on Cu/ZnO-based methanol synthesis catalysts Catalysis Letters. ,vol. 73, pp. 27- 31 ,(2001) , 10.1023/A:1009074219286
Melanie A. McNeil, Carl J. Schack, Robert G. Rinker, Methanol synthesis from hydrogen, carbon monoxide and carbon dioxide over a CuO/ZnO/Al2O3 catalyst Applied Catalysis. ,vol. 50, pp. 265- 285 ,(1989) , 10.1016/S0166-9834(00)80841-6
Johannes J. Meyer, Pepe Tan, Andreas Apfelbacher, Robert Daschner, Andreas Hornung, Modeling of a Methanol Synthesis Reactor for Storage of Renewable Energy and Conversion of CO2 – Comparison of Two Kinetic Models Chemical Engineering & Technology. ,vol. 39, pp. 233- 245 ,(2016) , 10.1002/CEAT.201500084
Ya-Fan Zhao, Yong Yang, Charles Mims, Charles H.F. Peden, Jun Li, Donghai Mei, Insight into methanol synthesis from CO2 hydrogenation on Cu(111): Complex reaction network and the effects of H2O Journal of Catalysis. ,vol. 281, pp. 199- 211 ,(2011) , 10.1016/J.JCAT.2011.04.012
C.V. Ovesen, B.S. Clausen, J. Schiøtz, P. Stoltze, H. Topsøe, J.K. Nørskov, Kinetic Implications of Dynamical Changes in Catalyst Morphology during Methanol Synthesis over Cu/ZnO Catalysts Journal of Catalysis. ,vol. 168, pp. 133- 142 ,(1997) , 10.1006/JCAT.1997.1629
Kevin J. Smith, "Synthesis of alcohols from carbon oxides and hydrogen. 1. Kinetics of the low-pressure methanol synthesis". Comments Industrial & Engineering Chemistry Research. ,vol. 26, pp. 400- 401 ,(1987) , 10.1021/IE00062A042
Takeshi Kubota, Itaru Hayakawa, Hirotaka Mabuse, Kozo Mori, Kenji Ushikoshi, Taiki Watanabe, Masahiro Saito, Kinetic study of methanol synthesis from carbon dioxide and hydrogen Applied Organometallic Chemistry. ,vol. 15, pp. 121- 126 ,(2001) , 10.1002/1099-0739(200102)15:2<121::AID-AOC106>3.0.CO;2-3
D. E. Mears, Tests for Transport Limitations in Experimental Catalytic Reactors Industrial & Engineering Chemistry Process Design and Development. ,vol. 10, pp. 320- 320 ,(1971) , 10.1021/I260040A020
Edward L. Kunkes, Felix Studt, Frank Abild-Pedersen, Robert Schlögl, Malte Behrens, Hydrogenation of CO2 to methanol and CO on Cu/ZnO/Al2O3: Is there a common intermediate or not? Journal of Catalysis. ,vol. 328, pp. 43- 48 ,(2015) , 10.1016/J.JCAT.2014.12.016
Bjerne S. Clausen, Jakob Schi�tz, Lars Gr�b�k, Charlotte V. Ovesen, Karsten W. Jacobsen, Jens K. N�rskov, Henrik Tops�e, Wetting/ non-wetting phenomena during catalysis: Evidence from in situ on-line EXAFS studies of Cu-based catalysts Topics in Catalysis. ,vol. 1, pp. 367- 376 ,(1994) , 10.1007/BF01492289