Stability and equilibria of free radicals—III

作者: A.T. Balaban , P.T. Frangopol , M. Frangopol , N. Negoiţǎ

DOI: 10.1016/S0040-4020(01)92564-5

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摘要: Abstract Diarrylamines ArNHAr′ (Ar = 2,4,6-tri-, 2,6-di- or 2,4-dinitrophenyl, and Ar′ phenyl a with electron-donating substituents) were prepared; their IR UV spectra, electrooxidation electroreduction potentials studied. Oxidation of picryl- 2,6-dinitrophenyl-substituted compounds Ag2O affords paramagnetic solution giving ESR signals has MeO NR2 substituents. Radicals IVi Vi are stable even in crystalline state.

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