Chemical methods to produce mesoporous thin films with tunable properties

作者: G.J.A.A. Soler-Illia , D. Onna , P. Vensaus

DOI: 10.1016/B978-0-12-819718-9.00002-9

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摘要: Abstract Mesoporous thin films (MTFs) possess very high surface area, uniform organized pores, and tailored surfaces. Novel properties of such materials depend on the sizes mesopores (2–50 nm diameter range), pore-array architecture, interconnectivity wall nature, functionality, pore contents. These features can be finely controlled through chemical physical processes as sol-gel chemistry, self-assembly, local reactivity. structures explored in a variety applications, photocatalysts, separation membranes, perm-selective electrodes, drug delivery, optical sensors, or bioactive In this chapter, we present concise review characterizations these exciting discuss methodologies to produce them. We also describe interesting systems which design synthesis lead tunable MTFs with exploitable properties.

参考文章(118)
Paolo N. Catalano, Alejandro Wolosiuk, Galo J.A.A. Soler-Illia, Martín G. Bellino, Wired enzymes in mesoporous materials: A benchmark for fabricating biofuel cells Bioelectrochemistry. ,vol. 106, pp. 14- 21 ,(2015) , 10.1016/J.BIOELECHEM.2015.06.006
Gregor Mali, Matjaž Mazaj, Mojca Rangus, Galo J.A.A. Soler-Illia, Venčeslav Kaučič, Solid-State NMR investigation of formation of mesoporous thin films and powders Studies in Surface Science and Catalysis. ,vol. 174, pp. 949- 952 ,(2008) , 10.1016/S0167-2991(08)80046-8
G. J. A. A. Soler-Illia, E. L. Crepaldi, D. Grosso, D. Durand, C. Sanchez, Structural control in self-standing mesostructured silica oriented membranes and xerogels Chemical Communications. pp. 2298- 2299 ,(2002) , 10.1039/B207595D
Galo J. A. A. Soler-Illia, Eduardo L. Crepaldi, David Grosso, Clément Sanchez, Designed synthesis of large-pore mesoporous silica–zirconia thin films with high mixing degree and tunable cubic or 2D-hexagonal mesostructure J. Mater. Chem.. ,vol. 14, pp. 1879- 1886 ,(2004) , 10.1039/B316033E
David Grosso, Galo J. de A. A. Soler-Illia, Eduardo. L. Crepaldi, Florence Cagnol, Christophe Sinturel, Alexis Bourgeois, Aline Brunet-Bruneau, Heinz Amenitsch, Pierre A. Albouy, Clément Sanchez, Highly Porous TiO2 Anatase Optical Thin Films with Cubic Mesostructure Stabilized at 700 °C Chemistry of Materials. ,vol. 15, pp. 4562- 4570 ,(2003) , 10.1021/CM031060H
Alejandra Calvo, María Joselevich, Galo J.A.A. Soler-Illia, Federico J. Williams, Chemical reactivity of amino-functionalized mesoporous silica thin films obtained by co-condensation and post-grafting routes Microporous and Mesoporous Materials. ,vol. 121, pp. 67- 72 ,(2009) , 10.1016/J.MICROMESO.2009.01.005
Yoshiaki Sakatani, David Grosso, Lionel Nicole, Cédric Boissière, Galo J. de A. A. Soler-Illia, Clément Sanchez, Optimised photocatalytic activity of grid-like mesoporous TiO2films: effect of crystallinity, pore size distribution, and pore accessibility J. Mater. Chem.. ,vol. 16, pp. 77- 82 ,(2006) , 10.1039/B512824M
Paula C. Angelomé, Leandro Andrini, Mauricio E. Calvo, Félix Gregorio Requejo, Sara A. Bilmes, Galo J. A. A. Soler-Illia, Mesoporous Anatase TiO2 Films: Use of Ti K XANES for the Quantification of the Nanocrystalline Character and Substrate Effects in the Photocatalysis Behavior Journal of Physical Chemistry C. ,vol. 111, pp. 10886- 10893 ,(2007) , 10.1021/JP069020Z
Sung Yeun Choi, Marc Mamak, Georg von Freymann, Naveen Chopra, Geoffrey A. Ozin, Mesoporous bragg stack color tunable sensors. Nano Letters. ,vol. 6, pp. 2456- 2461 ,(2006) , 10.1021/NL061580M
Luca Malfatti, Martín G. Bellino, Plinio Innocenzi, Galo J. A. A. Soler-Illia, One-Pot Route to Produce Hierarchically Porous Titania Thin Films by Controlled Self-Assembly, Swelling, and Phase Separation Chemistry of Materials. ,vol. 21, pp. 2763- 2769 ,(2009) , 10.1021/CM900289C