Homogeneous hydrogenation of the –NN–, –CHN–, and –NO2groupings

作者: I. Jardine , F. J. McQuillin

DOI: 10.1039/C2970000626A

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摘要: Using the previously described (py)3RhCl3–NaBH4 catalyst in dimethylformamide with hydrogen, azobenzene is reduced to hydrazobenzene and slowly aniline, benzalaniline gives benzylaniline, nitrobenzene aniline; pyridine quinoline are hydrogenated give piperidine 1,2,3,4-tetrahydroquinoline respectively.

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