Fast preparation of nano-hydroxyapatite/superhydrophilic reduced graphene oxide composites for bioactive applications

作者: Hudson Zanin , Eduardo Saito , Fernanda Roberta Marciano , Helder Jose Ceragioli , Alessandro Eustaquio Campos Granato

DOI: 10.1039/C3TB20550A

关键词:

摘要: A method for the direct electrodeposition of globular nano-hydroxyapatite (nHAp) onto reduced graphene oxide (RGO) is presented and a model specific growth preference discussed. Results show that carboxyl (carboxylic acid)/carboxylate functional groups attached directly to RGO after oxygen plasma treatment were essential accelerate OH– formation deposition nHAp crystals. High resolution scanning electron microscopy, energy dispersive X-ray diffraction showed homogeneous, highly crystalline, stoichiometric crystals, with preferential in (002) plane direction, formed without any thermal treatment. The nHAp/RGO composites shown be an appropriate surface mesenchymal stem cell adhesion active membrane projections.

参考文章(52)
Pradyot Patnaik, Handbook of Inorganic Chemicals ,(1997)
Sujata Kale, Sybil Biermann, Claire Edwards, Catherine Tarnowski, Michael Morris, Michael William Long, Three-dimensional cellular development is essential for ex vivo formation of human bone. Nature Biotechnology. ,vol. 18, pp. 954- 958 ,(2000) , 10.1038/79439
G.K. Toworfe, R.J. Composto, I.M. Shapiro, P. Ducheyne, NUCLEATION AND GROWTH OF CALCIUM PHOSPHATE ON AMINE, CARBOXYL- AND HYDROXYL-SILANE SELF-ASSEMBLED MONOLAYERS Biomaterials. ,vol. 27, pp. 631- 642 ,(2006) , 10.1016/J.BIOMATERIALS.2005.06.017
Ren Hu, Changjian Lin, Haiyan Shi, Hui Wang, Electrochemical deposition mechanism of calcium phosphate coating in dilute Ca-P electrolyte system Materials Chemistry and Physics. ,vol. 115, pp. 718- 723 ,(2009) , 10.1016/J.MATCHEMPHYS.2009.02.022
R. Damodaran, B.M. Moudgil, Electrophoretic deposition of calcium phosphates from non-aqueous media Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 80, pp. 191- 195 ,(1993) , 10.1016/0927-7757(93)80198-N
Hudson Zanin, Alfredo Carlos Peterlevitz, Helder José Ceragioli, Ana Amélia Rodrigues, William Dias Belangero, Vitor Baranauskas, Magnetic and cytotoxic properties of hot-filament chemical vapour deposited diamond Materials Science and Engineering: C. ,vol. 32, pp. 2340- 2343 ,(2012) , 10.1016/J.MSEC.2012.07.005
Noam Eliaz, Moshe Eliyahu, Electrochemical processes of nucleation and growth of hydroxyapatite on titanium supported by real-time electrochemical atomic force microscopy. Journal of Biomedical Materials Research Part A. ,vol. 80, pp. 621- 634 ,(2007) , 10.1002/JBM.A.30944
M.R.T. Filgueiras, D. Mkhonto, N.H. de Leeuw, Computer simulations of the adsorption of citric acid at hydroxyapatite surfaces Journal of Crystal Growth. ,vol. 294, pp. 60- 68 ,(2006) , 10.1016/J.JCRYSGRO.2006.05.077
Jianfeng Shen, Min Shi, Na Li, Bo Yan, Hongwei Ma, Yizhe Hu, Mingxin Ye, Facile synthesis and application of Ag-chemically converted graphene nanocomposite Nano Research. ,vol. 3, pp. 339- 349 ,(2010) , 10.1007/S12274-010-1037-X