Solar water splitting with earth-abundant materials using amorphous silicon photocathodes and Al/Ni contacts as hydrogen evolution catalyst
作者： F. Urbain , V. Smirnov , J.-P. Becker , U. Rau , J. Ziegler
DOI: 10.1016/J.CPLETT.2015.08.018
关键词:
摘要: Abstract An all earth-abundant and precious metal-free photocathode based on a low-temperature fabricated amorphous silicon tandem junction is demonstrated to be an efficient device for solar water splitting. With particular designed Al/Ni layer stack as photocathode/electrolyte contact onset potential cathodic photocurrent of 1.7 V vs. RHE saturation density 7.2 mA/cm 2 were achieved. For high-cost alternative with Ag/Pt even higher performance demonstrated. Above we present approach dedicated photovoltaic electrochemical development
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Bernhard Kaiser, Dominic Fertig, Jürgen Ziegler, Joachim Klett, Sascha Hoch, Wolfram Jaegermann, Solar hydrogen generation with wide-band-gap semiconductors: GaP(100) photoelectrodes and surface modification. ChemPhysChem. ,vol. 13, pp. 3053- 3060 ,(2012) , 10.1002/CPHC.201200432
Adam C. Nielander, Matthew R. Shaner, Kimberly M. Papadantonakis, Sonja A. Francis, Nathan S. Lewis, A taxonomy for solar fuels generators Energy and Environmental Science. ,vol. 8, pp. 16- 25 ,(2015) , 10.1039/C4EE02251C
V. Smirnov, A. Lambertz, S. Tillmanns, F. Finger, p- and n-type microcrystalline silicon oxide (μc-SiOx:H) for applications in thin film silicon tandem solar cells1 Canadian Journal of Physics. ,vol. 92, pp. 932- 935 ,(2014) , 10.1139/CJP-2013-0640
Brian Seger, Anders B. Laursen, Peter C. K. Vesborg, Thomas Pedersen, Ole Hansen, Søren Dahl, Ib Chorkendorff, Hydrogen Production Using a Molybdenum Sulfide Catalyst on a Titanium‐Protected n+p‐Silicon Photocathode Angewandte Chemie. ,vol. 51, pp. 9128- 9131 ,(2012) , 10.1002/ANIE.201203585
Lihao Han, Ibadillah A. Digdaya, Thom W. F. Buijs, Fatwa F. Abdi, Zhuangqun Huang, Rui Liu, Bernard Dam, Miro Zeman, Wilson A. Smith, Arno H. M. Smets, Gradient dopant profiling and spectral utilization of monolithic thin-film silicon photoelectrochemical tandem devices for solar water splitting Journal of Materials Chemistry. ,vol. 3, pp. 4155- 4162 ,(2015) , 10.1039/C4TA05523C
H. Tributsch, Layer-Type Transition Metal Dichalcogenides - a New Class of Electrodes for Electrochemical Solar Cells Berichte der Bunsengesellschaft für physikalische Chemie. ,vol. 81, pp. 361- 369 ,(1977) , 10.1002/BBPC.19770810403
Félix Urbain, Vladimir Smirnov, Jan-Philipp Becker, Uwe Rau, Friedhelm Finger, Jürgen Ziegler, Bernhard Kaiser, Wolfram Jaegermann, a-Si:H/µc-Si:H tandem junction based photocathodes with high open-circuit voltage for efficient hydrogen production Journal of Materials Research. ,vol. 29, pp. 2605- 2614 ,(2014) , 10.1557/JMR.2014.308
Gary Hodes, Photoelectrochemical Cell Measurements: Getting the Basics Right. Journal of Physical Chemistry Letters. ,vol. 3, pp. 1208- 1213 ,(2012) , 10.1021/JZ300220B
Oomman K. Varghese, Sudhir Ranjan, Craig A. Grimes, Light, Water, Hydrogen: The Solar Generation of Hydrogen by Water Photoelectrolysis ,(2011)
Yuriy Pihosh, Ivan Turkevych, Kazuma Mawatari, Jin Uemura, Yutaka Kazoe, Sonya Kosar, Kikuo Makita, Takeyoshi Sugaya, Takuya Matsui, Daisuke Fujita, Masahiro Tosa, Michio Kondo, Takehiko Kitamori, Photocatalytic generation of hydrogen by core-shell WO3/BiVO4 nanorods with ultimate water splitting efficiency Scientific Reports. ,vol. 5, pp. 11141- 11141 ,(2015) , 10.1038/SREP11141