摘要: An electrochemical promotion of heterogeneously catalyzed reactions (EPOC) became possible through the use porous metal electrodes interfaced to a solid electrolyte. The EPOC effect has been demonstrated for more than 100 reaction systems. Surface science investigations showed that physical basis lies in electrochemically induced spillover transported ionic species onto surface electrodes. This report summarizes progress which achieved mechanistic understanding effect.
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Richard M. Lambert, Federico Williams, Alejandra Palermo, Mintcho S. Tikhov, Modelling alkali promotion in heterogeneous catalysis: in situ electrochemical control of catalytic reactions Topics in Catalysis. ,vol. 13, pp. 91- 98 ,(2000) , 10.1023/A:1009076720641
Elena R. Savinova, Constantinos G. Vayenas, Andrzej Więckowski, Catalysis and Electrocatalysis at Nanoparticle Surfaces ,(2009)
M. P. Kiskinova, Poisoning and Promotion in Catalysis Based on Surface Science Concepts and Experiments ,(1991)
J. NICOLE, CH. COMNINELLIS, Electrochemical promotion of IrO2 catalyst activity for the gas phase combustion of ethylene Journal of Applied Electrochemistry. ,vol. 28, pp. 223- 226 ,(1998) , 10.1023/A:1003295112211
Carl Wagner, Adsorbed Atomic Species as Intermediates in Heterogeneous Catalysis Advances in Catalysis. ,vol. 21, pp. 323- 381 ,(1970) , 10.1016/S0360-0564(08)60567-2
Gonzalo Prieto, Ferdi Schüth, Bridging the gap between insightful simplicity and successful complexity: From fundamental studies on model systems to technical catalysts Journal of Catalysis. ,vol. 328, pp. 59- 71 ,(2015) , 10.1016/J.JCAT.2014.12.009
R. Schloegl, R. C. Schoonmaker, M. Muhler, G. Ertl, BRIDGING THE "MATERIAL GAP" BETWEEN SINGLE CRYSTAL STUDIES AND REAL CATALYSIS Catalysis Letters. ,vol. 1, pp. 237- 241 ,(1988) , 10.1007/BF00766181
J. K. Norskov, F. Abild-Pedersen, F. Studt, T. Bligaard, Density functional theory in surface chemistry and catalysis. Proceedings of the National Academy of Sciences of the United States of America. ,vol. 108, pp. 937- 943 ,(2011) , 10.1073/PNAS.1006652108
Jürgen Janek, Marcus Rohnke, Bjoern Luerßen, Ronald Imbihl, Promotion of catalytic reactions by electrochemical polarization Physical Chemistry Chemical Physics. ,vol. 2, pp. 1935- 1941 ,(2000) , 10.1039/B000002G
H. Pöpke, E. Mutoro, C. Raiß, B. Luerßen, M. Amati, M.K. Abyaneh, L. Gregoratti, J. Janek, The role of platinum oxide in the electrode system Pt(O2)/yttria-stabilized zirconia Electrochimica Acta. ,vol. 56, pp. 10668- 10675 ,(2011) , 10.1016/J.ELECTACTA.2011.04.057