Ionic liquids as solvents

作者: Kenneth Richard Seddon , Charles Mackintosh Gordon , Graham Victor Hutson , Mark Fields

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摘要: A method of dissolving in an ionic liquid a metal initial oxidation state below its maximum state, characterised that the reacts with and oxidises it to higher state. The may be form compound thereof irradiated nuclear fuel comprising UO2 and/or PuO2 as well fission products. typically is nitrate-based, for example pyridinium or substituted imidazolium nitrate, contains Bronstead Franklin acid increase oxidising power nitrate. Suitable acids are HNO3, H2SO4 [NO+]. Imidazolium nitrates certain one aspect invention.

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