Oxygen Diffusion Enables Anti-Wear Boundary Film Formation on Titanium Surfaces in Zinc-Dialkyl-Dithiophosphate (ZDDP)-Containing Lubricants

作者: Jun Qu , Peter J. Blau , Jane Y. Howe , Harry M. Meyer III

DOI: 10.1016/J.SCRIPTAMAT.2009.02.009

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摘要: This paper reports a wear reduction by up to six orders of magnitude for Ti-6Al-4V alloy when treated an oxygen diffusion (OD) process and subsequently tested in zinc-dialkyl-dithiophosphate (ZDDP)-containing lubricant. In addition case hardening, it is discovered that OD enables the formation anti-wear boundary film on titanium surface. Transmission electron microscopy surface chemical analyses revealed this has two-layer structure comprising amorphous oxide interlayer ZDDP-based top with complex compounds.

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