Parametric line profile analysis for in situ XRD of SnO2 materials: Separation of size and strain contributions
作者： R.G. Pavelko , F. Gispert-Guirado , E. Llobet
DOI: 10.1016/J.SSI.2013.11.028
关键词:
摘要: Abstract Parametric line profile analysis has been used to separate size and strain contributions the peak broadening of in situ X-ray diffractograms recorded during isothermal annealing nanocrystalline SnO 2 materials. Of five kinetic models for crystallite growth, simplified generalised parabolic model was found be closest transmission electron microscopy (TEM) sizes resulting expected (exponential) relaxation strain. Crystallite growth evolution pure Pd-doped compared discussed regarding possible mechanisms. It shown that lattice strain, despite being very low, leads overestimation activation energy if not considered integral breadth analysis.
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sci-hub.se 参考文章(59)
Anthony D Rollett, Gregory S Rohrer, F John Humphreys, Recrystallization and Related Annealing Phenomena ,(1996)
G. Korotcenkov, B.K. Cho, The role of grain size on the thermal instability of nanostructured metal oxides used in gas sensor applications and approaches for grain-size stabilization Progress in Crystal Growth and Characterization of Materials. ,vol. 58, pp. 167- 208 ,(2012) , 10.1016/J.PCRYSGROW.2012.07.001
E Zolotoyabko, JLM Rupp, LJ Gauckler, None, Interrelationship between grain size-induced and strain-induced broadening of X-ray diffraction profiles: What we can learn about nanostructured materials? Scripta Materialia. ,vol. 66, pp. 190- 193 ,(2012) , 10.1016/J.SCRIPTAMAT.2011.10.037
E.R. Leite, J.A. Cerri, E. Longo, J.A. Varela, C.A. Paskocima, Sintering of ultrafine undoped SnO2 powder Journal of The European Ceramic Society. ,vol. 21, pp. 669- 675 ,(2001) , 10.1016/S0955-2219(00)00250-8
M. Fantini, I.L. Torriani, C. Constantino, Influence of the substrate on the crystalline properties of sprayed tin dioxide thin films Journal of Crystal Growth. ,vol. 74, pp. 439- 442 ,(1986) , 10.1016/0022-0248(86)90135-1
G.E.S. Brito, C.V. Santilli, S.H. Pulcinelli, A.F. Craievich, SAXS measurements of the porosity in Cu(II)-doped SnO2 xerogels during crystallization Journal of Non-crystalline Solids. ,vol. 217, pp. 41- 47 ,(1997) , 10.1016/S0022-3093(97)00137-3
Roman G. Pavelko, Helen Daly, Christopher Hardacre, Alexey A. Vasiliev, Eduard Llobet, Interaction of water, hydrogen and their mixtures with SnO2 based materials: the role of surface hydroxyl groups in detection mechanisms Physical Chemistry Chemical Physics. ,vol. 12, pp. 2639- 2647 ,(2010) , 10.1039/B921665K
GES Brito, V Briois, Sandra Helena Pulcinelli, Celso Valentim Santilli, EXAFS and XRD Study of the Structural Evolution during Isothermal Sintering of SnO2 Xerogels Journal of Sol-Gel Science and Technology. ,vol. 8, pp. 269- 274 ,(1997) , 10.1023/A:1026410313051
Abhijit Ghosh, Dharni D. Upadhyaya, Ram Prasad, Primary Crystallization Behavior of ZrO2–Y2O3 Powders: In Situ Hot-Stage XRD Technique Journal of the American Ceramic Society. ,vol. 85, pp. 2399- 2403 ,(2002) , 10.1111/J.1151-2916.2002.TB00471.X
A. Gajović, K. Furić, G. Štefanić, S. Musić, In situ high temperature study of ZrO2 ball-milled to nanometer sizes Journal of Molecular Structure. ,vol. 744, pp. 127- 133 ,(2005) , 10.1016/J.MOLSTRUC.2004.10.038